SOLVENT-FREE CONDITIONS AS AN ECO-FRIENDLY STRATEGY FOR SYNTHESIS OF ORGANOPHOSPHORUS COMPOUNDS

被引：7

作者：

Marandi, Ghasem ^{[1
]}

Torbati, Niloufar Akbarzadeh ^{[2
]}

Heydari, Reza ^{[3
]}

Hazeri, Nourallah ^{[3
]}

Habibi-Khorassani, Sayyed Mostafa ^{[4
]}

Maghsoodlou, Malek Taher ^{[3
]}

Adrom, Belghais ^{[3
]}

Skelton, Brian W. ^{[5
]}

Makha, Mohamed ^{[5
]}

机构：

[1] Urmia Univ, Shahid Bakeri High Educ Ctr Miandoab, Orumiyeh, Iran

[2] Univ Sistan & Baluchestan, Fac Sci, Dept Inorgan Chem, Zahedan, Iran

[3] Univ Sistan & Baluchestan, Fac Sci, Dept Organ Chem, Zahedan, Iran

[4] Univ Sistan & Baluchestan, Fac Sci, Dept Phys Organ Chem, Zahedan, Iran

[5] Univ Western Australia, Chem Sch Biomed Biomol & Chem Sci, Perth, WA 6009, Australia

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2012年 / 187卷 / 12期

关键词：

Solvent-free conditions; acetylenic ester; Ph3P; stable phosphorus ylides; 1,4-diionic compounds; ONE-POT SYNTHESIS; STABILIZED PHOSPHORUS YLIDES; GEL CATALYZED CONVERSION; STEREOSELECTIVE O-VINYLATION; MICROWAVE-INDUCED CONVERSION; AROMATIC CARBOXYLIC-ACIDS; X-RAY-STRUCTURE; SILICA-GEL; 3-COMPONENT REACTION; ACETYLENIC ESTERS;

D O I：

10.1080/10426507.2012.690116

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of diverse NH- and CH-acids are used for a one-pot synthesis of stable phosphorus ylides and 1,4-diionic organophosphorus compounds by trapping of the zwitterionic intermediate from the reaction between triphenylphosphine and dialkyl acetylenedicarboxylates under solvent-free conditions. The structural geometry for one of the products was confirmed by single crystal X-ray diffraction analysis.

引用

页码：1450 / 1461

页数：12

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