Synthesis, crystal structure and properties of a new strontium cadmium diborate

被引：4
|
作者：
Cao, Jian [1 ,2 ]
Gao, Junyu [1 ,2 ]
Pan, Shilie [1 ]
Yu, Hongwei [1 ,2 ]
Zhao, Wenwu [1 ,2 ]
Yang, Zhihua [1 ]
机构：
[1] Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2012年 / 392卷
基金：
中国国家自然科学基金;
关键词：
SrCdB2O5; Crystal structure; Diborate; X-ray diffraction; OPTICAL-PROPERTIES; GENERATION; GROWTH; BORATE; POLAR;
D O I：
10.1016/j.ica.2012.03.012
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new compound, SrCdB2O5, has been grown by the high temperature solution method from the SrO-Cd-B2O3 system for the first time. It crystallizes in the orthorhombic system, space group Pbca with unit-cell parameters a = 12.010(4) angstrom, b = 5.795(2) angstrom, c = 12.677(4) angstrom, Z = 8, volume = 882.4(5) angstrom(3). Its structure is solved by the direct methods and refined to R-1 = 0.0256 and wR(2) = 0.0727. The new structure contains an infinite three-dimensional matrix that is built from B2O5 units and CdO6 and SrO9 polyhedra. Spectrum properties, thermal analysis and theoretical calculations on electronic structure of SrCdB2O5 were reported. (C) 2012 Elsevier B. V. All rights reserved.
引用
收藏
页码：459 / 464
页数：6
相关论文
共 50 条
  • [1] CRYSTAL STRUCTURE OF STRONTIUM DIBORATE
    KROGHMOE, J
    NATURE, 1965, 206 (4984) : 613 - &
  • [2] Synthesis, crystal structure and properties of a new lead calcium diborate
    Cao, Jian
    Pan, Shilie
    Gao, Junyu
    Huang, Zhenjun
    Dong, Xiaoyu
    Zhang, Min
    SOLID STATE SCIENCES, 2012, 14 (07) : 948 - 951
  • [3] CRYSTAL STRUCTURE OF STRONTIUM DIBORATE SR0.2B203
    KROGHMOE, J
    ACTA CHEMICA SCANDINAVICA, 1964, 18 (09): : 2055 - &
  • [4] The crystal structure of melamine diborate
    Kawasaki, T
    Kuroda, Y
    Nishikawa, H
    JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 1996, 104 (10) : 935 - 938
  • [5] Synthesis, crystal structure and spectroscopic properties of a new chiral cadmium (II) malate
    Beghidja, Adel
    Beghidja, Chahrazed
    Rogez, Guillaume
    Rabu, Pierre
    Welter, Richard
    INORGANIC CHEMISTRY COMMUNICATIONS, 2008, 11 (09) : 1088 - 1090
  • [6] Synthesis, Crystal Structure, and Characterization of a Congruent Melting Compound Magnesium Strontium Diborate MgSrB2O5
    Guo, Xinfeng
    Wu, Hongping
    Pan, Shilie
    Yang, Zhihua
    Yu, Hongwei
    Zhang, Bingbing
    Han, Jian
    Zhang, Fangyuan
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2014, 640 (8-9): : 1805 - 1809
  • [7] CRYSTAL STRUCTURE OF CADMIUM DIBORATE CDO .2B2O3
    IHARA, M
    KROGHMOE, J
    ACTA CRYSTALLOGRAPHICA, 1966, 20 : 132 - &
  • [8] Crystal structure of cadmium dizinc diborate, CdZn2(BO3)2
    Zhang, Fan
    Shen, De-Zhong
    Shen, Guang-Qiu
    Wang, Xiao-Qing
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2008, 223 (01): : 3 - 4
  • [9] Synthesis,Crystal Structure and Fluorescent Properties of Silver and Cadmium Complexes
    王庆伟
    刘博
    隋薇
    Chinese Journal of Structural Chemistry, 2018, 37 (03) : 453 - 460
  • [10] Growth, crystal structure and optical properties of layered dibarium cadmium diborate, Ba2Cd(BO3)2
    Zhang, Min
    Pan, Shilie
    Han, Jian
    Yang, Yun
    Cui, Liang
    Zhou, Zhongxiang
    JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (23) : 6696 - 6699
12345