Organic-inorganic hybrid complexes based on a Keggin-type polyoxoanion

被引：4
|
作者：
Lan, Qing [1 ]
Lu, Ying [1 ]
Li, Yang-Guang [1 ]
Tan, Hua-Qiao [1 ]
Liu, Ding [1 ]
Wang, En-Bo [1 ]
机构：
[1] NE Normal Univ, Dept Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China
来源：
TRANSITION METAL CHEMISTRY | 2012年 / 37卷 / 05期
基金：
中国国家自然科学基金;
关键词：
3D ARCHITECTURES; POLYOXOMETALATE; FRAMEWORK; CLUSTERS; COPPER; CATALYST; ALPHA;
D O I：
10.1007/s11243-012-9608-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two organic-inorganic hybrid complexes based on a Keggin-type polyoxoanion, namely [Ni-2(H2O)(2)(bipy)(4)(Hbipy)][AlW12O40]center dot 7H(2)O 1 and [Ni2Cl2(bipy)(3)(Hbipy)(2)][SiW12O40]center dot 2.5H(2)O 2 (bipy = 4,4'-bipy), have been synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, and single-crystal X-ray diffraction. Complexes 1 and 2 possess similar 2D layer structures, constructed from 1D zigzag chains {Ni(bipy)} (n) (2n+) and alternatively arranged Keggin anion and bipy linkers. Photocatalytic investigations indicate that both 1 and 2 exhibit photocatalytic activity for the degradation of Rhodamine B.
引用
收藏
页码：445 / 451
页数：7
相关论文
共 50 条
  • [1] Organic–inorganic hybrid complexes based on a Keggin-type polyoxoanion
    Qing Lan
    Ying Lu
    Yang-Guang Li
    Hua-Qiao Tan
    Ding Liu
    En-Bo Wang
    Transition Metal Chemistry, 2012, 37 : 445 - 451
  • [2] A new organic-inorganic hybrid compound based on lanthanide-organic chain and Keggin-type polyoxometalate
    Hao, Xiu-Li
    Luo, Ming-Fa
    Wang, Xin
    Feng, Xiao-Jia
    Li, Yang-Guang
    Wang, Yong-Hui
    Wang, En-Bo
    INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (11) : 1698 - 1702
  • [3] The catalytic epimerization of glucose to mannose over an organic-inorganic hybrid based on Keggin-type phosphomolybdate
    Han, Chunyang
    Ji, Jing-Jing
    Xia, Haian
    Fei, Baoli
    NEW JOURNAL OF CHEMISTRY, 2024, 48 (26) : 11674 - 11681
  • [4] New organic-inorganic hybrid assemblies based on metal-bis(betaine) coordination complexes and Keggin-type polyoxometalates
    Hao, Xiu-Li
    Ma, Yuan-Yuan
    Wang, Yong-Hui
    Zhou, Wen-Zhe
    Li, Yang-Guang
    INORGANIC CHEMISTRY COMMUNICATIONS, 2014, 41 : 19 - 24
  • [5] Synthesis, characterization and photoluminescence properties of an organic-inorganic hybrid monolacunary Keggin-type polyoxotungstate
    Wang, Ke
    Feng, Shuo
    Ma, Pengtao
    INORGANIC CHEMISTRY COMMUNICATIONS, 2021, 129
  • [6] Syntheses and structures of two new organic-inorganic hybrid lanthanide derivatives based on Keggin-type polyoxometalates
    Li, Dehui
    Sun, Bo
    Qi, Weichen
    Xiao, Jinglei
    Yang, Jing
    Han, Xiying
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2016, 624 (01) : 183 - 189
  • [7] An Organic-Inorganic Hybrid Based on Keggin-Type Polyoxometalate and Hypoxanthine: Synthesis, Structure, Stability, and Electrochemistry Properties
    Ma, Feng-Ji
    Yuan, Bai-Qing
    Li, Meng-Rou
    Li, Shu-Jun
    Zhang, Shuang-Shuang
    Liu, Lei-Lei
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2016, 642 (17): : 925 - 929
  • [8] Three organic-inorganic hybrid complexes based on the Wells-Dawson polyoxoanion
    Wang, Xiao-Lan
    Lu, Ying
    Meng, Jing-Xin
    Wang, En-Bo
    Fu, Hai
    TRANSITION METAL CHEMISTRY, 2011, 36 (02) : 201 - 206
  • [9] Insights into the Structure of Keggin-Type Polyoxometalate-Based Organic-Inorganic Hybrid Materials: The Actual Ratio of Organic Cations to Heteropolyanions
    Hong, Cheng-Bin
    Wang, Tong
    Liu, Haichao
    INORGANIC CHEMISTRY, 2023, 62 (10) : 4054 - 4065
  • [10] Two Organic-Inorganic Hybrids Assembled from Transition-Metal Complexes and Keggin-Type Silicotungstates
    Luo, Jie
    Liu, Jian-Cai
    Shao, Bo
    Chen, Li-Juan
    Zhao, Jun-Wei
    JOURNAL OF CLUSTER SCIENCE, 2015, 26 (06) : 2005 - 2022
12345