Synergistic cooperative effect of CF3SO2Na and bis(2-butoxyethyl)ether towards selective oxygenation of sulfides with molecular oxygen under visible-light irradiation

被引：105

作者：

Liu, Kai-Jian ^{[1
]}

Wang, Zheng ^{[1
]}

Lu, Ling-Hui ^{[1
]}

Chen, Jin-Yang ^{[2
]}

Zeng, Fei ^{[1
]}

Lin, Ying-Wu ^{[2
]}

Cao, Zhong ^{[3
]}

Yu, Xianyong ^{[4
]}

He, Wei-Min ^{[1
]}

机构：

[1] Hunan Univ Sci & Engn, Dept Chem & Bioengn, Yongzhou 425100, Peoples R China

[2] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China

[3] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Duns, Changsha 410114, Peoples R China

[4] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Xiangtan 411201, Peoples R China

来源：

GREEN CHEMISTRY | 2021年 / 23卷 / 01期

关键词：

INDUCED DEOXYGENATIVE C2-SULFONYLATION; REDUCTIVE MINISCI REACTION; QUINOLINE N-OXIDES; RADICAL CYCLIZATION; ELECTRON-TRANSFER; OXIDATION; SULFONES; QUINOXALIN-2(1H)-ONES; SULFOXIDES; AMBIENT;

D O I：

10.1039/d0gc02663h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A safe, practical and eco-friendly method for the switchable synthesis of sulfoxides and sulfones through visible-light-initiated oxygenation of sulfides at ambient temperature under transition-metal-, additives-free and minimal solvent conditions. The synergistic catalytic efforts between CF3SO2Na and 2-butoxyethyl ether represents the key promoting factor for the reaction.

引用

页码：496 / 500

页数：5

共 9 条

[1] Selective remote C-H trifluoromethylation of aminoquinolines with CF3SO2Na under visible light irradiation in the absence of an external photocatalyst
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[2] Visible-Light-Induced DDQ-Catalyzed Fluorocarbamoylation Using CF3SO2Na and Oxygen
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[3] New photocatalysts based on cadmium and zinc sulfides for hydrogen evolution from aqueous Na2S-Na2SO3 solutions under irradiation with visible light
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[4] New photocatalysts based on cadmium and zinc sulfides for hydrogen evolution from aqueous Na2S-Na2SO3 solutions under irradiation with visible light
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[8] Synergistic effect of cocatalyst and S-scheme heterojunction over 2D/2D g-C3N4/MoS2 heterostructure coupled Cu nanoparticles for selective photocatalytic CO2 reduction to CO under visible light irradiation
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[9] Synergistic effect of iodine doped TiO2 nanoparticle/g-C3N4 nanosheets with upgraded visible-light-sensitive performance toward highly efficient and selective photocatalytic oxidation of aromatic alcohols under blue LED irradiation
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