Rh2(OAC)4-catalyzed regioselective intermolecular C-H insertion reactions:: Novel synthesis of 2-pyrrol-3′-yloxindoles

被引：0
|
作者：
Muthusamy, S [1 ]
Gunanathan, C [1 ]
机构：
[1] Cent Salt & Marine Chem Res Inst, Bhavnagar 364002, Gujarat, India
来源：
SYNLETT | 2002年 / 11期
关键词：
C-H insertion reaction; oxindole; pyrrole; rhodium(II) acetate;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Regioselective synthesis of 2-pyrrol-3'-yloxindoles has been achieved by the reactions of cyclic diazo carbonyl compounds la-e with pyrrole and substituted pyrroles (2a-d) in the presence of rhodium(II) acetate catalyst via intermolecular C-H insertion reaction.
引用
收藏
页码：1783 / 1786
页数：4
相关论文
共 50 条
  • [1] The Rh2(OAc)4 catalysed C-H insertion in chiral ester diazoanilides
    Wee, A. G. H.
    Liu, B.
    Tetrahedron Letters, 37 (02):
  • [2] Steric and electronic influences on the diastereoselectivity of the Rh2(OAc)4-catalyzed C-H insertion in chiral ester diazoanilides:: Synthesis of chiral, nonracemic 4-substituted 2-pyrrolidinones
    Wee, AGH
    Liu, BS
    McLeod, DD
    JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (13): : 4218 - 4227
  • [3] The Rh2(OAc)4-catalyzed reactions of 3-trifluoromethy1-4-diazopyrazolinones with aromatic compounds
    Fan, Huafang
    Zhang, Zhenhua
    Li, Xinjin
    Zhao, Jingwei
    Gao, Jinming
    Zhu, Shizheng
    TETRAHEDRON, 2013, 69 (08) : 1978 - 1986
  • [4] Analyzing Site Selectivity in Rh2(esp)2-Catalyzed Intermolecular C-H Amination Reactions
    Bess, Elizabeth N.
    DeLuca, Ryan J.
    Tindall, Daniel J.
    Oderinde, Martins S.
    Roizen, Jennifer L.
    Du Bois, J.
    Sigman, Matthew S.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (15) : 5783 - 5789
  • [5] Rh2(OAc)4-catalyzed reaction of 2-(2-carbonylvinyl)-3-phenyl-2H-azirines with diazo esters
    Zavyalov, K. V.
    Novikov, M. S.
    Khlebnikov, A. F.
    Rostovskii, N. V.
    Starova, G. L.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2017, 53 (08) : 1214 - 1221
  • [6] Rh2(OAc)4-catalyzed reaction of α-diazocarbonyl compounds with 2-carbonyl-substituted 2H-azirines
    Zavyalov, Kirill V.
    Novikov, Mikail S.
    Khlebnikov, Alexander F.
    Yufit, Dmitry S.
    TETRAHEDRON, 2013, 69 (23) : 4546 - 4551
  • [7] Rh2(OAc)4-catalyzed reactions of α-diazoimides:: a simple and novel synthesis of mono- and bis(2,3-fused perhydrooxazol-4-one) systems
    Muthusamy, S
    Gunanathan, C
    CHEMICAL COMMUNICATIONS, 2003, (03) : 440 - 441
  • [8] Rh2(OAc)4-catalyzed reaction of 1,3-dioxanes with methyl diazoacetate
    Sultanova, RM
    Katashova, VR
    Petrov, DA
    Fatykhov, AA
    Zlotsky, SS
    Dokichev, VA
    RUSSIAN CHEMICAL BULLETIN, 2001, 50 (05) : 865 - 867
  • [9] Rh2(OAc)4-catalyzed reaction of 2-(2-carbonylvinyl)-3-phenyl-2H-azirines with diazo esters
    K. V. Zavyalov
    M. S. Novikov
    А. F. Khlebnikov
    N. V. Rostovskii
    G. L. Starova
    Russian Journal of Organic Chemistry, 2017, 53 : 1214 - 1221
  • [10] Rh2(OAc)4-catalyzed reaction of 1,3-dioxanes with methyl diazoacetate
    R. M. Sultanova
    V. R. Katashova
    D. A. Petrov
    A. A. Fatykhov
    S. S. Zlotsky
    V. A. Dokichev
    Russian Chemical Bulletin, 2001, 50 : 865 - 867
12345