Conductivity studies of LiCF3SO3 doped PVA: PVdF blend polymer electrolyte

被引：42
|
作者：
Tamilselvi, P. [1 ]
Hema, M. [1 ]
机构：
[1] Kamaraj Coll Engn & Technol, Dept Phys, Virudunagar 626001, Tamil Nadu, India
来源：
PHYSICA B-CONDENSED MATTER | 2014年 / 437卷
关键词：
Impedance spectroscopy; Dielectric; Polymer electrolyte; Ionic conductivity; IONIC-CONDUCTIVITY; AC CONDUCTIVITY; IMPEDANCE; TEMPERATURE; CRYSTALLINE; BEHAVIOR; GLASSES; PHASE;
D O I：
10.1016/j.physb.2013.12.028
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
Different composition of lithium ion conducting PVA: Miff: Lithium trillate (LiCF3S03) polymer electrolytes have been prepared by solution casting technique. Dielectric and conductivity studies have been carried out for the prepared samples. The addition of salt into the polymer matrix increases the ionic conductivity of blend polymer electrolytes. The conductivity analysis reveals 80PVA: 20PVc1F: 15LiCF3S03 polymer electrolyte exhibits the maximum ionic conductivity of 2.7 x 10-3 S cm-1 at 303 K. The temperature dependence of ionic conductivity for all the composition of PVA: PVdF: LiCF3S03 polymer films obey Arrhenius relation. Low activation energy has been obtained for highest conducting sample. The dielectric spectra show absolute 0-relaxation peak. (C) 2013 Elsevier B.V. All rights reserved,
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页码：53 / 57
页数：5
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