Two novel luminescent lanthanide sulfate-carboxylates with an unusual 2-D bamboo-raft-like structure based on the linkages of left- and right-handed helical tubes involving in situ decarboxylation

被引：160

作者：

Sun, YQ

Zhang, J

Yang, GY ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

[2] Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 18期

关键词：

D O I：

10.1039/b602034h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two novel 2-D bamboo-raft-like lanthanide luminescent materials [Ln(Himc)(SO4)(H2O)](L-n=Dy, Eu; H(2)imc=4-imidazolecarboxylic acid), constructed from alternate left- and right-handed helical tubes, were synthesized and characterized; interestingly, H(2)imc came from the in situ decarboxylation of the 4,5-imidazoledicarboxylic acid (H(3)imdc) in the hydrothermal reactions.

引用

页码：1947 / 1949

页数：3