Green Chemistry of Polyurethanes: Synthesis, Structure, and Functionality of Triglycerides of Soybean Oil with Epoxy and Cyclocarbonate Groups-Renewable Raw Materials for New Urethanes

被引：10

作者：

Levina, M. A. ^{[1
]}

Miloslavskii, D. G. ^{[2
]}

Pridatchenko, M. L. ^{[3
]}

Gorshkov, A. V. ^{[1
]}

Shashkova, V. T. ^{[1
]}

Gotlib, E. M. ^{[2
]}

Tiger, R. P. ^{[1
]}

机构：

[1] Russian Acad Sci, Semenov Inst Chem Phys, Moscow 119991, Russia

[2] Kazan Natl Res Technol Univ, Kazan 420015, Russia

[3] Russian Acad Sci, Talrose Inst Energy Problems Chem Phys, Moscow 119334, Russia

来源：

POLYMER SCIENCE SERIES B | 2015年 / 57卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

CYCLIC CARBONATES; MODEL REACTION; AMINES; MECHANISM; ROUTE; KINETICS;

D O I：

10.1134/S156009041506010X

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of cyclocarbonate-containing oligomers for non-isocyanate polyurethanes via the catalytic reaction of carbon dioxide with epoxidized soybean oil has been described. It has been shown via the mass-spectrometric method that the oligomers, which are triglycerides of epoxide- and cyclocarbonate-containing derivatives of carboxylic acids, are characterized by an extremely wide composition distribution, reflecting almost the entire set of components contained in natural raw materials. The presence of 25 types of triglycerides of unsaturated (oleic, linoleic, and linolenic) and saturated (stearic and palmitic) carboxylic acids in various combinations in oligomers has been found. The functionality of oligomers at epoxy and cyclocarbonate groups and the problems of the use of plant raw materials for the synthesis of non-isocyanate polyurethanes are discussed.

引用

页码：584 / 592

页数：9

共 6 条

[1] Green chemistry of polyurethanes: Synthesis, structure, and functionality of triglycerides of soybean oil with epoxy and cyclocarbonate groups—renewable raw materials for new urethanes
M. A. Levina
D. G. Miloslavskii
M. L. Pridatchenko
A. V. Gorshkov
V. T. Shashkova
E. M. Gotlib
R. P. Tiger
Polymer Science Series B, 2015, 57 : 584 - 592
[2] Green Chemistry of Polyurethanes: Synthesis, Functional Composition, and Reactivity of Cyclocarbonate-Containing Sunflower Oil Triglycerides—Renewable Raw Materials for New Urethanes
M. A. Levina
D. G. Miloslavskii
M. V. Zabalov
M. L. Pridatchenko
A. V. Gorshkov
V. T. Shashkova
V. L. Krasheninnikov
R. P. Tiger
Polymer Science, Series B, 2019, 61 : 540 - 549
[3] Green Chemistry of Polyurethanes: Synthesis, Functional Composition, and Reactivity of Cyclocarbonate-Containing Sunflower Oil Triglycerides-Renewable Raw Materials for New Urethanes
Levina, M. A.
Miloslayskii, D. G.
Zabalov, M., V
Pridatchenko, M. L.
Gorshkov, A., V
Shashkova, V. T.
Krasheninnikov, V. L.
Tiger, R. P.
POLYMER SCIENCE SERIES B, 2019, 61 (05) : 540 - 549
[4] Kinetics and quantum chemical aspects of the mechanism of the guanidine (TBD) catalyzed aminolysis of cyclocarbonate containing soybean oil triglycerides as the model process of green chemistry of polyurethanes
Mira A. Levina
Maxim V. Zabalov
Vadim G. Krasheninnikov
Roald P. Tiger
Reaction Kinetics, Mechanisms and Catalysis, 2020, 129 : 65 - 83
[5] Kinetics and quantum chemical aspects of the mechanism of the guanidine (TBD) catalyzed aminolysis of cyclocarbonate containing soybean oil triglycerides as the model process of green chemistry of polyurethanes
Levina, Mira A.
Zabalov, Maxim, V
Krasheninnikov, Vadim G.
Tiger, Roald P.
REACTION KINETICS MECHANISMS AND CATALYSIS, 2020, 129 (01) : 65 - 83
[6] Palm oil as a renewable raw material in the synthesis of new polymeric materials through the epoxy fusion process
Sienkiewicz, A.
Czub, P.
Milo, A.
EXPRESS POLYMER LETTERS, 2021, 15 (07): : 582 - 599

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