Temperature-responsive enzyme-polymer nanoconjugates with enhanced catalytic activities in organic media

被引：70
|
作者：
Zhu, Jingying [1 ]
Zhang, Yifei [1 ]
Lu, Diannan [1 ]
Zare, Richard N. [2 ]
Ge, Jun [1 ]
Liu, Zheng [1 ]
机构：
[1] Tsinghua Univ, Dept Chem Engn, Beijing 100084, Peoples R China
[2] Stanford Univ, Dept Chem, Stanford, CA 94305 USA
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 54期
基金：
中国国家自然科学基金;
关键词：
LIPASE NANOGEL; NANOBIOCATALYSIS; IMMOBILIZATION; NANOREACTORS; PROTEIN;
D O I：
10.1039/c3cc42493f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A general approach for preparing enzyme-polymer nanoconjugates that respond to temperature in organic media is presented. These nanoconjugates readily dissolve in organic solvents for homogenous catalysis at 40 degrees C and showed greatly enhanced apparent catalytic activities. The recovery of the soluble enzyme-polymer nanoconjugates is accomplished by temperature-induced precipitation.
引用
收藏
页码：6090 / 6092
页数：3
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