Properties and Applications of Choline-Based Deep Eutectic Solvents

被引:0
|
作者
Zhang Yingying [1 ,2 ]
Lu Xiaohua [1 ]
Feng Xin [1 ]
Shi Yijun [1 ,3 ]
Ji Xiaoyan [2 ]
机构
[1] Nanjing Univ Technol, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Peoples R China
[2] Lulea Univ Technol, Div Energy Sci Energy Engn, S-97187 Lulea, Sweden
[3] Lulea Univ Technol, Div Machine Element, S-97187 Lulea, Sweden
关键词
choline; ionic liquids; freezing point; solubility; viscosity; surface tension; conductivity; ACIDIC IONIC LIQUIDS; IONOTHERMAL SYNTHESIS; ROOM-TEMPERATURE; MELTING-POINTS; PHYSICOCHEMICAL PROPERTIES; CARBON-DIOXIDE; ORGANIC FRAMEWORKS; BINARY-MIXTURES; GAS SOLUBILITY; HOLE THEORY;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Choline-based deep eutectic solvents (DESs) are considered as a new class of ionic liquids. Comparing to traditional ionic liquids, choline-based DESs are low-toxic, biodegradable, and the price is generally low, which make them more and more attractive in green chemistry and industrial chemistry. In the current work, the properties of choline-based DESs, such as freezing point, melting point, solubility, viscosity, surface tension and conductivity, were collected and summarized. The dependences of these properties with different factors, such as temperature, mole ratios and water content, and the models which can be used to predict the properties were studied and discussed. The applications of choline-based DESs in the area of lubrication, functional material preparation, electrochemistry, organic synthesis and catalytic conversion of biomass were introduced. Finally, the problems and difficulties in research and applications were illustrated and then prospective was provided.
引用
收藏
页码:881 / 892
页数:12
相关论文
共 124 条
  • [1] Electrofinishing of metals using eutectic based ionic liquids
    Abbott, A. P.
    Ryder, K. S.
    Koenig, U.
    [J]. TRANSACTIONS OF THE INSTITUTE OF METAL FINISHING, 2008, 86 (04): : 196 - 204
  • [2] Electrodeposition of nickel using eutectic based ionic liquids
    Abbott, A. P.
    El Ttaib, K.
    Ryder, K. S.
    Smith, E. L.
    [J]. TRANSACTIONS OF THE INSTITUTE OF METAL FINISHING, 2008, 86 (04): : 234 - 240
  • [3] Abbott A.P., 2002, [No title captured], Patent No. [WO 02/26701 (A2), 0226701]
  • [4] Application of hole theory to define ionic liquids by their transport properties
    Abbott, Andrew P.
    Harris, Robert C.
    Ryder, Karl S.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (18): : 4910 - 4913
  • [5] Electrodeposition of zinc-tin alloys from deep eutectic solvents based on choline chloride
    Abbott, Andrew P.
    Capper, Glen
    McKenzie, Katy J.
    Ryder, Karl S.
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2007, 599 (02) : 288 - 294
  • [6] Application of ionic liquids to the electrodeposition of metals
    Abbott, Andrew P.
    McKenzie, Katy J.
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (37) : 4265 - 4279
  • [7] Electropolishing of stainless steels in a choline chloride based ionic liquid: an electrochemical study with surface characterisation using SEM and atomic force microscopy
    Abbott, Andrew P.
    Capper, Glen
    McKenzie, Katy J.
    Glidle, Andrew
    Ryder, Karl S.
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (36) : 4214 - 4221
  • [8] Solubility of metal oxides in deep eutectic solvents based on choline chloride
    Abbott, Andrew P.
    Capper, Glen
    Davies, David L.
    McKenzie, Katy J.
    Obi, Stephen U.
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2006, 51 (04): : 1280 - 1282
  • [9] Glycerol eutectics as sustainable solvent systems
    Abbott, Andrew P.
    Harris, Robert C.
    Ryder, Karl S.
    D'Agostino, Carmine
    Gladden, Lynn F.
    Mantle, Mick D.
    [J]. GREEN CHEMISTRY, 2011, 13 (01) : 82 - 90
  • [10] Electrodeposition of copper composites from deep eutectic solvents based on choline chloride
    Abbott, Andrew P.
    El Ttaib, Khalid
    Frisch, Gero
    McKenzie, Katy J.
    Ryder, Karl S.
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 11 (21) : 4269 - 4277