The reactivities of dehydroalanine derivatives towards 1,3-dienyl cobaloxime complex: new routes to functionalised carbocyclic amino acids

被引：16

作者：

Chai, CLL ^{[1
]}

Johnson, RC ^{[1
]}

Koh, J ^{[1
]}

机构：

[1] Australian Natl Univ, Dept Chem, Canberra, ACT 0200, Australia

来源：

TETRAHEDRON | 2002年 / 58卷 / 05期

基金：

澳大利亚研究理事会;

关键词：

amino acids and derivatives; Diels-Alder;

D O I：

10.1016/S0040-4020(01)01160-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reactivities and selectivities of the Diels-Alder reactions of acyclic dehydroalanine esters and cyclic dehydroalanines derived from piperazine-2,5-diones with 1,3-dienyl cobaloxime complex are reported. From our studies we demonstrate the use of the activated organocobalt diene in a 'combinatorial' approach to the synthesis of functionalised cyclic amino acids and derivatives from a single cycloaddition reaction. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：975 / 982

页数：8

共 3 条

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