Double C-H activation in pentamethylcyclopentadienylruthenium complexes

被引：5

作者：

OLeary, SR ^{[1
]}

Adams, H ^{[1
]}

Maitlis, PM ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 09期

关键词：

D O I：

10.1039/a701373f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two methyls in each eta(5)-C5Me5 are activated in [{(eta(5)-C5Me5)RuCl2}(2)] 1 [by (i) air, (ii? N-chlorosuccinimide and (iir? air]; after carbonylation a mixture of the 1,3- and 1,2-isomers [{eta(5)-C5Me3(CH2Cl)(2)}Ru(CO)(2)Cl] 4a,b is obtained; the X-ray structure of 4a is determined.

引用

页码：895 / 896

页数：2

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