Thermodynamic studies of U(VI) complexation with glutardiamidoxime for sequestration of uranium from seawater

被引：76
|
作者：
Tian, Guoxin [1 ]
Teat, Simon J. [2 ]
Rao, Linfeng [1 ]
机构：
[1] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA 94720 USA
来源：
DALTON TRANSACTIONS | 2013年 / 42卷 / 16期
关键词：
EQUILIBRIUM-CONSTANTS; EXTRACTION; AMIDOXIMES; RECOVERY; SORBERS;
D O I：
10.1039/c3dt32940b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Glutardiamidoxime (H2B), a diamidoxime ligand that has implications in sequestering uranium from seawater, forms strong complexes with UO22+. Five U(VI) complexes were identified in 3% NaCl solution. The stability constants and the enthalpies of complexation were measured by potentiometry and microcalorimetry. The competition between glutardiamidoxime and carbonate for complexing U(VI) in 3% NaCl was also studied in comparison with the cyclic glutarimidedioxime ligand (H(2)A) previously studied.
引用
收藏
页码：5690 / 5696
页数：7
相关论文
共 50 条
  • [1] Complexation of uranium(VI) with glutarimidoxioxime: thermodynamic and computational studies
    Endrizzi, Francesco
    Melchior, Andrea
    Tolazzib, Marilena
    Rao, Linfeng
    DALTON TRANSACTIONS, 2015, 44 (31) : 13835 - 13844
  • [2] Thermodynamic studies of U(VI) complexation with acetate in dimethyl sulfoxide.
    Rao, LF
    Zanonato, P
    Di Bernardo, P
    Bismondo, A
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 225 : U65 - U65
  • [3] Complexation of glutarimidedioxime with Fe(III), Cu(II), Pb(II), and Ni(II), the competing ions for the sequestration of U(VI) from seawater
    Sun, Xiaoqi
    Xu, Chao
    Tian, Guoxin
    Rao, Linfeng
    DALTON TRANSACTIONS, 2013, 42 (40) : 14621 - 14627
  • [4] Thermodynamic study on the U(VI) complexation with dicarboxylates by calorimetry
    Kirishima, A.
    Onishi, Y.
    Sato, N.
    Tochiyama, O.
    RADIOCHIMICA ACTA, 2008, 96 (9-11) : 581 - 589
  • [5] Thermodynamic study of the complexation of uranium(VI) with nitrate at variable temperatures
    Rao, Linfeng
    Tian, Guoxin
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2008, 40 (06): : 1001 - 1006
  • [6] Uranium(VI) complexation with trans-1,2-cyclohexanediaminetetraacetic acid in solution: thermodynamic and structural studies
    Chen, Wen
    Chen, Baihua
    Liu, Bijun
    Yang, Yuchuan
    Tu, Jun
    Wei, Hongyuan
    Yang, Yanqiu
    Li, Xingliang
    Luo, Shunzhong
    JOURNAL OF COORDINATION CHEMISTRY, 2020, 73 (24) : 3382 - 3394
  • [7] Polyethylenimine embellished multiwalled carbon nanotube (MWCNTs) for efficiently enhancing sequestration of uranium(VI) from seawater
    Liu, Chang
    Li, Ye
    Liu, Shuang
    Zhou, Yuzhi
    Li, Bolin
    Liu, Dongxue
    Fu, Chengbin
    Ye, Lingfeng
    JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2022, 10 (05):
  • [8] Engineered Sorbents for Selective Uranium Sequestration from Seawater
    Singh, Bhupendra Kumar
    Asim, Muhammad
    Salkenova, Zarina
    Pak, Donghun
    Um, Wooyong
    ACS ES&T WATER, 2024, 4 (02): : 325 - 345
  • [9] Complexation of glutarimidedioxime with V(V), a major competing ion for the extraction of U(VI) from seawater
    Leggett, Christina
    Rao, Linfeng
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [10] Complexation of Uranium(VI) by Gluconate in Acidic Solutions: a Thermodynamic Study with Structural Analysis
    Zhang, Zhicheng
    Helms, Gregory
    Clark, Sue B.
    Tian, Guoxin
    Zanonato, PierLuigi
    Rao, Linfeng
    INORGANIC CHEMISTRY, 2009, 48 (08) : 3814 - 3824
12345