Phase equilibria in the Cu2S-{Sb,Bi}2S3-Ga2S3 and Cu2S-{Sb,Bi}2S3-In2S3 systems at 673 K

被引：0

作者：

Olekseyuk, I. D. ^{[1
]}

Zhbankov, O. Ye. ^{[1
]}

Kumanska, Yu. O. ^{[1
]}

Tkachuk, V. O. ^{[1
]}

机构：

[1] Volyn State Univ, Dept Gen & Inorgan Chem, UA-43009 Lutsk, Ukraine

来源：

POLISH JOURNAL OF CHEMISTRY | 2006年 / 80卷 / 05期

关键词：

phase diagram; solid solution; lattice parameters; crystal structure;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phase equilibria in the Cu2S-{Sb,Bi}(2)S-3-Ga2S3 and Cu2S-{Sb,Bi}(2)S-3-In2S3 systems at 673 K were investigated by X-ray powder diffraction and their isothermal sections were constructed. No quaternary compounds or continuous solid solutions were found. The homogeneity region of the CuIn5S8 phase in quasibinary Cu2S-In2S3 system was determined in the range 7.3-17.2 mol.% Cu2S. The Rietveld refinement of the crystal structure CuGa5S8 has been performed, using powder diffraction pattern in the zinc blende model (SG F (4) over bar 3m, a = 0.52246(2) nm).

引用

页码：817 / 823

页数：7

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