Esterolytic activity of metal complexes of 2,6-diacetylpyridine dioxime

被引：0

作者：

Tagle, PG ^{[1
]}

Yatsimirsky, AK ^{[1
]}

机构：

[1] UNIV NACL AUTONOMA MEXICO, FAC QUIM, MEXICO CITY 04510, DF, MEXICO

来源：

POLYHEDRON | 1997年 / 16卷 / 05期

关键词：

ester hydrolysis; oxime; metal complexes; catalysis;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The rate constants of the cleavage of 4-nitrophenyl acetate (4-O2NC6H4O2CCH3) by the complexes of 2,6-diacetylpyridine dioxime with Ni-II, Hg-II, Zn-II, Pb-II, Mn-II and Cd-II range from 2 to ca 6000 times higher than that of the free ligand under the same conditions. Complexation of the oxime ligand with Co-II and Cu-II does not affect the reaction rate. The complex with Cd-II operates in a catalytic regime with respect to the oxime ligand. The activities of the complexes with different metals, excluding Co-II, correlate with those of metallocarboxypeptidases towards an ester substrate. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：877 / 879

页数：3

共 50 条

[1] Esterolytic activity of metal complexes, of 2,6-diacetylpyridine dioxime
Tagle, P. G.
Yatsimirsky, A. K.
[J]. Polyhedron, 1996, 16 (05)
[2] Kinetics and mechanism of ester hydrolysis by metal complexes of 2,6-diacetylpyridine dioxime
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[3] COPPER(II) COMPLEXES DERIVED FROM 2,6-DIACETYLPYRIDINE DIOXIME
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[4] NICKEL(II) AND NICKEL(IV) COMPLEXES OF 2,6-DIACETYLPYRIDINE DIOXIME
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[6] METAL COMPLEXES DERIVED FROM SUBSTITUTED HYDRAZONES OF 2,6-DIACETYLPYRIDINE
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ROBINSON, MA
BUSCH, DH
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[8] TRANSITION-METAL CHEMISTRY OF OXIME CONTAINING LIGANDS, .28. MANGANESE(II) COMPLEXES OF 2,6-DIACETYLPYRIDINE DIOXIME
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[10] SYNTHESIS AND CHARACTERIZATION OF SOME LANTHANIDE(III) CHELATES OF 2,6-DIACETYLPYRIDINE DIOXIME
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