Syntheses, Structures, and Fluorescence of Two Novel 2D Zinc(II) Layered Frameworks Based on 3-Amino-1, 2, 4-triazole

被引：3

作者：

Gao, Jin-Ying ^{[1
]}

Xiong, Xia-Hua ^{[2
]}

Chen, Chu-Jun ^{[1
]}

Xie, Wei-Ping ^{[1
]}

Ran, Xing-Rui ^{[1
]}

Yue, Shan-Tang ^{[1
]}

机构：

[1] S China Normal Univ, Sch Chem & Environm, Guangzhou 510006, Guangdong, Peoples R China

[2] S China Univ Technol, Coll Mat Sci Engn, Guangzhou 510640, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2013年 / 639卷 / 3-4期

基金：

中国国家自然科学基金;

关键词：

Coordination polymers; Hydrothermal synthesis; Zinc; Luminescent properties; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; LUMINESCENT; CHEMISTRY; LIGANDS; SERIES; PH; ARCHITECTURES; CONSTRUCTION; SEPARATION;

D O I：

10.1002/zaac.201200422

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two 2D zinc(II) layered coordination polymer compounds [Zn2(atz)2(na)2]n (1), and [Zn(atz)(ina)]n (2) (Hatz = 3-amino-1H-1, 2, 4-triazole, na = nicotinic acid, ina = isonicotinic acid) were synthesized and structurally characterized by elemental analysis, FT-IR, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD), and single-crystal X-ray diffraction. The interconnection of a coplanar six-membered hexagonal ring and a 16-membered non-planar chair-like ring results in a 2D sheet with (4, 82) topological network. Hydrogen bonds connect the neighboring planes into 3D supramolecular architectures. Furthermore, both complexes exhibit strong luminescent properties in the solid state at room temperature.

引用

页码：582 / 586

页数：5

共 50 条

[1] Two new d10 2D layered frameworks based on 1,2,4-triazole bridge: Syntheses, structures, and fluorescence
Liu, Bing
Zhang, Xiu-Cheng
INORGANIC CHEMISTRY COMMUNICATIONS, 2008, 11 (10) : 1162 - 1165
[2] 3-AMINO-1,2,4-TRIAZOLE - 1,2,4-TRIAZOLE, 3-AMINO
ALLEN, CFH
BELL, A
ORGANIC SYNTHESES, 1946, 26 : 11 - 12
[3] Syntheses and properties of the Co(II), Ni(II), Zn(II) and Cd(II) complexes with 3-amino-1,2,4-triazole, 4-amino-1,2,4-triazole, 3,5-diamino-1,2,4-triazole and 3-amino-5-methylthio-1,2,4-triazole
Gabryszewski, M
Wieczorek, B
POLISH JOURNAL OF CHEMISTRY, 1999, 73 (12) : 2061 - 2066
[4] Syntheses, Crystal Structures, and Fluorescence Properties of Two 2D→2D Coordination Polymers Based on the Flexible 4-Substituted Bis(1,2,4-triazole) Ligand
PENG Yanfen
LIU Tianbao
WU Qiuyan
Wuhan University Journal of Natural Sciences, 2019, 24 (01) : 8 - 14
[5] COPPER(II) COMPLEXES WITH 3-AMINO-1,2,4-TRIAZOLE
GINZBURG, VV
GLEBOV, AN
ZHURNAL NEORGANICHESKOI KHIMII, 1993, 38 (05): : 866 - 870
[6] Synthesis and characterization of the copper(II) complexes with 3-amino-1,2,4-triazole, 4-amino-1,2,4-triazole and 3-amino-5-methylthio-1,2,4-triazole
Gabryszewski, M
POLISH JOURNAL OF CHEMISTRY, 1998, 72 (12) : 2519 - 2523
[7] Silver(I) complexes with 1,2,4-triazole, 1-ethyl-1,2,4-triazole, 3-amino-1,2,4-triazole, 4-amino-1,2,4-triazole and 3,5-diamino-1,2,4-triazole
Gabryszewski, M
Wieczorek, B
POLISH JOURNAL OF CHEMISTRY, 1998, 72 (10) : 2352 - 2355
[8] Electrolytic oxidation of 1H-1,2,4-triazole, 3-amino-1,2,4-triazole, and 4-amino-1,2,4-triazole for energetic material synthesis
Mori, Kanae
Kumasaki, Mieko
Atobe, Mahito
SCIENCE AND TECHNOLOGY OF ENERGETIC MATERIALS, 2021, 82 (02) : 44 - 49
[9] Syntheses and structures of 3d4d heterometallic coordination polymers based on 4-amino-1,2,4-triazole
Gou, Yu-Ting
Yue, Fan
Chen, Hua-Mei
Liu, Gang
Sun, Du-Cheng
JOURNAL OF COORDINATION CHEMISTRY, 2013, 66 (11) : 1889 - 1896
[10] Rigid, microporous 3D molecular frameworks derived from 3-amino-1,2,4-triazole
Schlueter, J. A.
Funk, R. J.
Geiser, U.
JOURNAL OF LOW TEMPERATURE PHYSICS, 2006, 142 (3-4) : 429 - 432

← 1 2 3 4 5 →