Postsynthetic modification of metal-organic framework as a highly efficient and recyclable catalyst for three-component (aldehyde-alkyne-amine) coupling reaction

被引：51
|
作者：
Yang, Jin [1 ]
Li, Pinhua [1 ]
Wang, Lei [1 ,2 ]
机构：
[1] Huaibei Normal Univ, Dept Chem, Huaibei 235000, Anhui, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2012年 / 27卷
基金：
中国国家自然科学基金;
关键词：
Cu(I)-MOF catalyst; Metal-organic framework; Postsynthetic modification; Heterogeneous catalyst; COVALENT MODIFICATION; TERMINAL ALKYNES; FUNCTIONALIZATION; MOFS; DESIGN;
D O I：
10.1016/j.catcom.2012.06.023
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A MOF-supported Cu(I) catalyst bearing N,O-chelating ligand was prepared through postsynthetic modification of IRMOF-3 and used as an efficient heterogeneous catalyst for three-component coupling reaction of aldehyde, alkyne, and amine. The catalyst exhibited both high catalytic activity and stability for the reaction and the framework of Cu(I) catalyst was mainly maintained after the catalyst was reused for four times. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：58 / 62
页数：5
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