Aqueous chemical growth of Cu2ZnSnS4 (CZTS) thin films: Air annealing and photoelectrochemical properties

被引：36
|
作者：
Shinde, N. M. [1 ]
Deshmukh, P. R. [1 ]
Patil, S. V. [1 ]
Lokhande, C. D. [1 ]
机构：
[1] Shivaji Univ, Dept Phys, Thin Film Phys Lab, Kolhapur 416004, MS, India
来源：
MATERIALS RESEARCH BULLETIN | 2013年 / 48卷 / 05期
关键词：
Cu2ZnSnS4; Thin film; Chemical synthesis; X-ray diffraction; Optical properties; IONIC LAYER ADSORPTION; OPTICAL-PROPERTIES; DEPOSITION;
D O I：
10.1016/j.materresbull.2012.12.053
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
In present investigation, Cu2ZnSnS4(CZTS) thin films have been deposited on to glass substrates by novel chemical successive ionic layer adsorption and reaction (SILAR) method. The effect of air annealing in the temperature range between 573 and 773 K on the structural, morphological, optical and electrical properties has been studied. The X-ray diffraction studies revealed the formation of polycrystalline CZTS films. The surface morphological study showed smooth, compact and uniform film formation after annealing formation. The band gap was in between range from 1.5 to 1.8 eV depending on annealing temperature. The thermo emf measurement revealed that the CZTS exhibits p-type electrical conductivity. Further, photoactivity of CZTS thin films was tested by forming the photoelectrochemical cell. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1760 / 1766
页数：7
相关论文
共 50 条
  • [1] Properties of spray deposited Cu2ZnSnS4 (CZTS) thin films
    Shinde, N. M.
    Deokate, R. J.
    Lokhande, C. D.
    [J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2013, 100 : 12 - 16
  • [2] Chemical Spray Pyrolyzed Kesterite Cu2ZnSnS4 (CZTS) Thin Films
    Khalate, S. A.
    Kate, R. S.
    Deokate, R. J.
    [J]. 62ND DAE SOLID STATE PHYSICS SYMPOSIUM, 2018, 1942
  • [3] Effect of deposition temperature on the properties of Cu2ZnSnS4 (CZTS) thin films
    Khalate, S. A.
    Kate, R. S.
    Kim, J. H.
    Pawar, S. M.
    Deokate, R. J.
    [J]. SUPERLATTICES AND MICROSTRUCTURES, 2017, 103 : 335 - 342
  • [4] A chemical approach for synthesis of photoelectrochemically active Cu2ZnSnS4 (CZTS) thin films
    Suryawanshi, M. P.
    Shin, S. W.
    Ghorpade, U. V.
    Guray, K. V.
    Agawane, G. L.
    Hong, Chang Woo
    Yun, Jae Ho
    Patil, P. S.
    Kim, Jin Hyeok
    Moholkar, A. V.
    [J]. SOLAR ENERGY, 2014, 110 : 221 - 230
  • [5] Effect of annealing process on the properties of Cu2ZnSnS4 thin films
    Seboui, Zeineb
    Gassoumi, Abdelaziz
    Cuminal, Yvan
    Kamoun-Turki, Najoua
    [J]. SUPERLATTICES AND MICROSTRUCTURES, 2014, 75 : 586 - 592
  • [6] Growth of Cu2ZnSnS4 (CZTS) thin films using short sulfurization periods
    Olgar, M. A.
    Tomakin, M.
    Kucukomeroglu, T.
    Bacaksiz, E.
    [J]. MATERIALS RESEARCH EXPRESS, 2019, 6 (05)
  • [7] Soft annealing effect on the properties of sputter grown Cu2ZnSnS4 (CZTS) thin films for solar cell applications
    Pandharkar, Subhash
    Punde, Ashvini
    Nasane, Mamta
    Doiphode, Vidya
    Shinde, Pratibha
    Vairale, Priti
    Hase, Yogesh
    Bhorde, Ajinkya
    Waghmare, Ashish
    Rondiya, Sachin
    Prasad, Mohit
    Jadkar, Sandesh
    [J]. MATERIALS TODAY-PROCEEDINGS, 2021, 34 : 690 - 696
  • [8] Growth of Cu2ZnSnS4 thin films by hybrid chemical approach
    Jayasree, Y.
    Kumar, Y. B. Kishore
    Babu, G. Suresh
    Bhaskar, P. Uday
    [J]. PHYSICA B-CONDENSED MATTER, 2021, 618
  • [9] Novel chemical route for chemical bath deposition of Cu2ZnSnS4 (CZTS) thin films with stacked precursor thin films
    Rana, Tanka Raj
    Shinde, N. M.
    Kim, Junho
    [J]. MATERIALS LETTERS, 2016, 162 : 40 - 43
  • [10] Effect of complexing agent on the properties of electrochemically deposited Cu2ZnSnS4 (CZTS) thin films
    Pawar, B. S.
    Pawar, S. M.
    Shin, S. W.
    Choi, D. S.
    Park, C. J.
    Kolekar, S. S.
    Kim, J. H.
    [J]. APPLIED SURFACE SCIENCE, 2010, 257 (05) : 1786 - 1791
12345