Phosphonitrilic chloride as an efficient reagent for the synthesis of β-sultams

被引：4
|
作者：
Zarei, Maaroof [1 ]
机构：
[1] Hormozgan Univ, Coll Sci, Dept Chem, Bandar Abbas 71961, Iran
来源：
TETRAHEDRON LETTERS | 2013年 / 54卷 / 09期
关键词：
beta-Sultam; Phosphonitrilic chloride; Sulfene; Schiff base; Cycloaddition; SUBSTITUTED 1,2-THIAZETIDINE 1,1-DIOXIDES; ASYMMETRIC-SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; CYCLOADDITION REACTIONS; BECKMANN REARRANGEMENT; ACID-DERIVATIVES; REACTIVITY; MECHANISM; LACTAMS; SULFONYLATION;
D O I：
10.1016/j.tetlet.2012.12.069
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel and efficient route for the conversion of imines and sulfonic acids into beta-sultams using phosphonitrilic chloride at room temperature in dry CH2Cl2 is described. Optimization of the conditions was performed. This method is very convenient and the water-soluble by-product is removed by simple aqueous work-up. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1100 / 1102
页数：3
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