Axially Aligned Confinement of 1,4-Bis(triethylammoniomethyl)benzene by Two p-Sulfonatocalix[4]arenes

被引：5

作者：

Ling, Irene ^{[1
]}

Alias, Yatimah ^{[1
]}

Rahim, Munirah Sufiyah Abdul ^{[1
]}

Skelton, Brian W. ^{[2
]}

Byrne, Lindsay T. ^{[2
]}

Raston, Colin L. ^{[3
]}

机构：

[1] Univ Malaya, Dept Chem, Fac Sci, Kuala Lumpur 50603, Malaysia

[2] Univ Western Australia, Ctr Microscopy Characterisat & Anal, Crawley, WA 6009, Australia

[3] Univ Western Australia, Ctr Strateg Nanofabricat, Sch Chem & Biochem, Crawley, WA 6009, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2012年 / 65卷 / 07期

基金：

澳大利亚研究理事会;

关键词：

CRYSTAL SUPRAMOLECULAR MOTIFS; MULTIPLE PHENYL EMBRACES; INTERMOLECULAR INTERACTIONS; SELF-COMPLEMENTARY; PH(4)P(+) CATIONS; CAPSULES; COMPLEXES; COORDINATION; CAVITY; SULFONATOCALIXARENES;

D O I：

10.1071/CH11449

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A multiple component bi-layer complex containing 1,4-bis(triethylammoniomethyl)benzene and mono-phosphonium cations, and p-sulfonatocalix[4]arene involves preferential binding of the ammonium cation in the cavities of two geometrically opposed calixarenes with the mono-phosphonium cation embedded within a bilayer of calixarenes. The complex has channels between bilayers similar to 14 angstrom in diameter which are lined with both polar sulfonate groups and the hydrophobic surface of the central part of the ammonium cation. H-1 NMR and 1D-ROESY experiments establish the formation of supermolecules of the bis-triethylammonium cation and two calixarenes in solution.

引用

页码：755 / 762

页数：8

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