Density and viscosity of several pure and water-saturated ionic liquids

被引:754
|
作者
Jacquemin, J [1 ]
Husson, P [1 ]
Padua, AAH [1 ]
Majer, V [1 ]
机构
[1] Univ Clermont Ferrand, Lab Thermodynam Solut & Polymeres, CNRS, F-63177 Clermont Ferrand, France
关键词
D O I
10.1039/b513231b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Densities and viscosities were measured as a function of temperature for six ionic liquids (1-butyl-3-methylimidazolium hexafluorophosphate, 1-butyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, 1-ethyl-3-methylimidazolium ethylsulfate and butyltrimethylammonium bis(trifluoromethylsulfonyl)imide. The density and the viscosity were obtained using a vibrating tube densimeter from Anton Paar and a rheometer from Rheometrics Scientific at temperatures up to 393 K and 388 K with an accuracy of 10(-3) g cm(-3) and 1%, respectively. The effect of the presence of water on the measured values was also examined by studying both dried and water-saturated samples. A qualitative analysis of the evolution of density and viscosity with cation and anion chemical structures was performed.
引用
收藏
页码:172 / 180
页数:9
相关论文
共 50 条
  • [1] Thermophysical properties of pure and water-saturated tetradecyltrihexylphosphonium-based ionic liquids
    Neves, Catarina M. S. S.
    Carvalho, Pedro J.
    Freire, Mara G.
    Coutinho, Joao A. P.
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2011, 43 (06): : 948 - 957
  • [2] A new insight into pure and water-saturated quaternary phosphonium-based carboxylate ionic liquids: Density, heat capacity, ionic conductivity, thermogravimetric analysis, thermal conductivity and viscosity
    Oster, K.
    Goodrich, P.
    Jacquemin, J.
    Hardacre, C.
    Ribeiro, A. P. C.
    Elsinawi, A.
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2018, 121 : 97 - 111
  • [3] Surface tension and refractive index of pure and water-saturated tetradecyltrihexylphosphonium-based ionic liquids
    Almeida, Hugo F. D.
    Lopes-da-Silva, Jose A.
    Freire, Mara G.
    Coutinho, Joao A. P.
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2013, 57 : 372 - 379
  • [4] Enzymatic resolution of (R, S)-naproxen in water-saturated ionic liquids
    Xin, JY
    Zhao, YJ
    Zheng, Y
    Xia, CG
    Li, SB
    CHINESE JOURNAL OF CATALYSIS, 2006, 27 (03) : 263 - 269
  • [5] Density and viscosity of pyridinium-based ionic liquids and their binary mixtures with water at several temperatures
    Mokhtarani, Babak
    Sharifi, Ali
    Mortaheb, Hamid Reza
    Mirzaei, Mojtaba
    Mafi, Morteza
    Sadeghian, Fatemeh
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2009, 41 (03): : 323 - 329
  • [6] Structural and Positional Isomerism Influence in the Physical Properties of Pyridinium NTf2-Based Ionic Liquids: Pure and Water-Saturated Mixtures
    Oliveira, Filipe S.
    Freire, Mara C.
    Carvalho, Pedro I.
    Coutinho, Joao A. P.
    Lopes, Jose N. Canongia
    Rebelo, Luis P. N.
    Marrucho, Isabel M.
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2010, 55 (10): : 4514 - 4520
  • [7] The Pressure–Viscosity Coefficient of Several Ionic Liquids
    A. S. Pensado
    M. J. P. Comuñas
    J. Fernández
    Tribology Letters, 2008, 31 : 107 - 118
  • [8] Densities, viscosities and derived thermophysical properties of water-saturated imidazolium-based ionic liquids
    Martins, Monia A. R.
    Neves, Catarina M. S. S.
    Kurnia, Kiki A.
    Carvalho, Pedro J.
    Rocha, Marisa A. A.
    Santos, Luis M. N. B. F.
    Pinho, Simao P.
    Freire, Mara G.
    FLUID PHASE EQUILIBRIA, 2016, 407 : 188 - 196
  • [9] Separation of precious metals by split-anion extraction using water-saturated ionic liquids
    Viet Tu Nguyen
    Riano, Sofia
    Binnemans, Koen
    GREEN CHEMISTRY, 2020, 22 (23) : 8375 - 8388
  • [10] The pressure-viscosity coefficient of several ionic liquids
    Pensado, A. S.
    Comunas, M. J. P.
    Fernandez, J.
    TRIBOLOGY LETTERS, 2008, 31 (02) : 107 - 118