Helicenophyrins: Expanded Carbaporphyrins Incorporating Aza[5]helicene and Heptacyclic S-Shaped Aza[5]helicene Motifs

被引：30

作者：

Szyszko, Bartosz ^{[1
]}

Przewoznik, Monika ^{[1
]}

Bialek, Michal J. ^{[1
]}

Bialonska, Agata ^{[1
]}

Chmielewski, Piotr J. ^{[1
]}

Cichos, Jakub ^{[1
]}

Latos-Grazynski, Lechoslaw ^{[1
]}

机构：

[1] Univ Wroclaw, Dept Chem, 14 F Joliot Curie St, PL-50383 Wroclaw, Poland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2018年 / 57卷 / 15期

关键词：

chirality; fused ring systems; helical structures; macrocycles; porphyrinoids; PORPHYRIN; ACENEPORPHYRINOIDS; SUBUNIT; FRAMEWORK; COMPLEX;

D O I：

10.1002/anie.201800879

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Incorporation of phenanthrene into a hexaphyrin(1.1.1.1.1.0) frame resulted in intramolecular ring fusion, thus giving rise to chiral helicenophyrins. These molecules contain helicene and porphyrin features by incorporating either an aza[5]helicene or heptacyclic S-shaped aza[5]helicene.

引用

页码：4030 / 4034

页数：5

共 15 条

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Upadhyay, Gourav M.
Bedekar, Ashutosh V.
TETRAHEDRON, 2015, 71 (34) : 5644 - 5649
[2] A Raman and SERS study on the interactions of aza[5]helicene and aza[6]helicene with a nanostructured gold surface
Zanchi, Chiara
Lucotti, Andrea
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Ossi, Paolo M.
Trusso, Sebastiano
Fontana, Francesca
Carminati, Greta
Rizzo, Simona
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VIBRATIONAL SPECTROSCOPY, 2020, 111
[3] Regioselective Desilylation of a π-Extended Aza[5]helicene
Ushiyama, Ayako
Shinokubo, Hiroshi
Hiroto, Satoru
CHEMISTRY LETTERS, 2019, 48 (09) : 1069 - 1072
[4] Synthesis and resolution of 2-amino-5-aza[6]helicene
Bhalodi, Esha H.
Patel, Krupa N.
Bedekar, Ashutosh, V
TETRAHEDRON, 2022, 114
[5] Helical Pitch Dependent Optical Properties of π-Extended Aza[5]helicene Radical Cations
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BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2020, 93 (11) : 1334 - 1338
[6] Functionalization of nanostructured gold substrates with chiral chromophores for SERS applications: The case of 5-Aza[5]helicene
Zanchi, Chiara
Lucotti, Andrea
Cancogni, Damiano
Fontana, Francesca
Trusso, Sebastiano
Ossi, Paolo M.
Tommasini, Matteo
CHIRALITY, 2018, 30 (07) : 875 - 882
[7] Study of confined 5-aza[5]helicene in ytterbium(III) bis(2-ethylhexyl) sulfosuccinate reversed micelles
Abbate, Sergio
Caronna, Tullio
Longo, Alessandro
Ruggirello, Angela
Liveri, Vincenzo Turco
JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (16): : 4089 - 4097
[8] Synthesis,characterization and electrochemical properties of 5-aza[5] helicene-CH2O-CO-MWCNTs nanocomposite
Fontana, F.
Melone, F.
Iannazzo, D.
Leonardi, S. G.
Neri, G.
NANOTECHNOLOGY, 2017, 28 (13)
[9] Synthesis of n-extended aza[5]helicene bearing AuI-acetylide at the outside or the inside of the helix
Hiroto, Satoru
Ura, Masaki
TETRAHEDRON LETTERS, 2023, 123
[10] Aza[5]helicene-Derived Semiconducting Polymers for Improved Performance in Perovskite Solar Cells: Exploring Energetic and Morphological Influences
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2024, 63 (18)

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