The Effects of Slag Compositions on the Coal Gasification Reaction in Molten Blast Furnace Slag

被引:14
|
作者
Li, P. [1 ]
Yu, Q. [1 ]
Qin, Q. [1 ]
Du, W. [1 ]
机构
[1] Northeastern Univ, Sch Met & Mat, Shenyang 110819, Liaoning, Peoples R China
关键词
blast furnace; coal gasification; economic and environmental evaluation; high temperature; molten slag; waste heat recovery; RECOVERY; HEAT; FEASIBILITY; SURFACE;
D O I
10.1080/15567036.2011.606870
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The char-CO2 gasification reactions in molten blast furnace slag were studied kinetically by the isothermal thermogravimetry using STA409PC thermal analyzer. The effects of slag compositions (SiO2, MgO, CaO, and Al2O3) on gasification reaction were investigated. The results showed that CaO has certain catalytic effects on gasification reaction; however, when the gasification reaction temperature reached a certain value, the catalytic effect of CaO on gasification could be neglected. MgO also played a catalytic role in the gasification reaction. In this experiment, the gasification reaction rate increased with increasing the MgO content from 8 to 10 mass%, whereas it decreased with increasing the MgO content from 10 to 12 mass%. SiO2 had no catalytic effect on gasification reaction.
引用
收藏
页码:73 / 79
页数:7
相关论文
共 50 条
  • [1] The Study of Coal Gasification in Molten Blast Furnace Slag
    Li, Peng
    Yu, Qingbo
    Qin, Qin
    Du, Wenya
    [J]. ENERGY TECHNOLOGY 2011: CARBON DIOXIDE AND OTHER GREENHOUSE GAS REDUCTION METALLURGY AND WASTE HEAT RECOVERY, 2011, : 77 - 83
  • [2] Adaptability of Coal Gasification in Molten Blast Furnace Slag on Coal Samples and Granularities
    Li, Peng
    Yu, Qingbo
    Qin, Qin
    Liu, Junxiang
    [J]. ENERGY & FUELS, 2011, 25 (12) : 5678 - 5682
  • [3] Feasibility Study for the System of Coal Gasification by Molten Blast Furnace Slag
    Li, Peng
    Qin, Qin
    Yu, Qingbo
    Du, Wenya
    [J]. MANUFACTURING SCIENCE AND ENGINEERING, PTS 1-5, 2010, 97-101 : 2347 - 2351
  • [4] Characterizations of the hot blast furnace slag on coal gasification reaction
    Duan, Wenjun
    Yu, Qingbo
    Liu, Junxiang
    Hou, Limin
    Xie, Huaqing
    Wang, Kun
    Qin, Qin
    [J]. APPLIED THERMAL ENGINEERING, 2016, 98 : 936 - 943
  • [5] Kinetics of CO2/Coal Gasification in Molten Blast Furnace Slag
    Li, Peng
    Yu, Qingbo
    Qin, Qin
    Lei, Wei
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (49) : 15872 - 15883
  • [6] Experimental study on gasification reaction characteristics of coal char with CO2 in molten blast furnace slag
    Yu, Qing-Bo
    Wang, Hui-Yao
    Li, Peng
    Qin, Qin
    [J]. Dongbei Daxue Xuebao/Journal of Northeastern University, 2013, 34 (06): : 840 - 844
  • [7] CO2 gasification rate analysis of coal in molten blast furnace slag-For heat recovery from molten slag by using a chemical reaction
    Li, Peng
    Lei, Wei
    Wu, Bin
    Yu, Qingbo
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (03) : 1607 - 1615
  • [8] The steam, gasification of coal with molten blast furnace slag as heat carrier and catalyst: Kinetic study
    Duan, Wenjun
    Yu, Qingbo
    Wu, Tianwei
    Yang, Fan
    Qin, Qin
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (42) : 18995 - 19004
  • [9] Experimental and kinetic study of steam gasification of low-rank coal in molten blast furnace slag
    Duan, Wenjun
    Yu, Qingbo
    Liu, Junxiang
    Wu, Tianwei
    Yang, Fan
    Qin, Qin
    [J]. ENERGY, 2016, 111 : 859 - 868
  • [10] Effect of coal treatment with molten blast furnace slag on char properties
    Shatokha, V. I.
    Sokolovskaya, I. V.
    [J]. IRONMAKING & STEELMAKING, 2013, 40 (08) : 635 - 637