Synthesis, Structure, and Magnetic and Luminescent Properties of Rare Earth Coordination Polymers Constructed from Mixed Dicarboxylates

被引：0
|
作者：
Abdulhadi, Nada [1 ]
Zhang Zhan-Rui [2 ]
Feng Guo-Qiang [3 ]
机构：
[1] Huazhong Univ Sci & Technol, Sch Phys, Wuhan 430074, Hubei, Peoples R China
[2] North Carolina State Univ, Dept Mech & Aerosp Engn, Raleigh, NC 27695 USA
[3] Hubei Univ Educ, Dept Phys & Mech & Elect Engn, Wuhan 430205, Hubei, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2019年 / 38卷 / 03期
基金：
中国国家自然科学基金;
关键词：
metal-organic framework; mixed carboxylates; rare earth metals; physical; METAL-ORGANIC FRAMEWORK; HYDROTHERMAL SYNTHESIS; COMPLEXES; BENZENEDICARBOXYLATES;
D O I：
10.14102/j.cnki.0254-5861.2011-2005
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three unique metal-organic framework coordination polymers, [Eu-2(bptc)(bdc)(2)(H2O)](n )(1), [Gd-2(bptc)(bdc)(2)(H2O)(4)](n) (2) and [Dy-2(bptc)(bdc)(2)(H2O)4](n) (3) (1,2-H2BDC = 1,2-benzenedicarboylic acid, H(2)bptc = 4,4'-biphenyldicarboxylic acid) were synthesized by mixing two different multi-carboxylic acids with Ln(2)O(3) (Ln = Eu, Gd and Dy) in hydrothermal condition. The three compounds are all three-dimensional and compounds 2 and 3 contain 4.289 x 6.507 angstrom(2) rectangular-shaped one-dimensional open channels along the a direction. Additionally, the magnetic, luminescent and thermogravimetric properties were studied in detail.
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页码：351 / 361
页数：11
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