Polymer-surfactant interaction and physico-chemical properties of polymethacrylic acid-Triton X-100 and polymethacrylic acid-poly(ethylene)oxide aqueous systems

被引：0

作者：

Tugay, A. V. ^{[1
]}

Zakordonskiy, V. P. ^{[1
]}

Soltys, M. M. ^{[1
]}

机构：

[1] Ivan Franko Natl Univ Lviv, Dept Phys & Colloid Chem, UA-79005 Lvov, Ukraine

来源：

POLISH JOURNAL OF CHEMISTRY | 2006年 / 80卷 / 06期

关键词：

polymethacrylic acid; Triton X-100; PEO; polymer-surfactant interaction; H-H binding complex; hydrophobic interaction;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The interaction of both Triton X-100 and poly(ethylene)oxide (PEO-2000) with polymethacrylic acid (PMAA) in aqueous solutions has been investigated by different methods: tensiometry, conductivity, viscometry, pH- and optical density measurement. The obtained results testify, that interaction of PMAA with the nonionic surfactants of different nature is accompanied by non-additive changes of physico-chemical properties and phase separation of binary systems. Thus, the character of influence of nonionic component depends on its nature. These changes take place in the clearly defined concentration ranges (1.10(-4)-1.10(-3) M for Triton X-100 and 1.10(-2)-1.10(-1) M for more high-molecular PEO-2000) and they are caused by intramolecular PMAA-surfactant complex formation. The experimental results clearly reveal, that important role in complex formation is played by hydrogen bonds. For investigated systems both the critical aggregation concentration (CAC) and the saturation concentration (C2) were calculated, and the idealized schema of the mechanism of polymer-surfactant interaction was proposed.

引用

页码：957 / 974

页数：18