Metal-ion-directed synthesis of sulfur-based macrocyclic helicates

被引：15
|
作者：
Matthews, RW [1 ]
McPartlin, M [1 ]
Scowen, IJ [1 ]
机构：
[1] UNIV N LONDON, SCH APPL CHEM, LONDON N7 8DB, ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 17期
关键词：
D O I：
10.1039/a704691j
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Schiff-base condensation of pyridine-2,6-dicarbaldehyde and 2[(2-{[(2-aminophenyl)sulfanyl]methyl}benzyl)sulfanyl]aniline led to different helical macrocyclic products depending on the template metal ion; a mono-helical [1 + 1] macrocyclic complex was generated in the presence of Ag-I and a double-helical [2 + 2] macrocyclic complex was generated in the presence of Cd-II.
引用
收藏
页码：2861 / 2863
页数：3
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