Effect of rotational excitation of NO on the stereodynamics for the reaction N (4S) plus NO (X2Π) → N2 (X3Σg-)+O (3P)*

被引：4
|
作者：
Ma Jian-Jun [1 ]
机构：
[1] Anhui Univ Technol, Dept Appl Phys, Maanshan 243002, Peoples R China
来源：
ACTA PHYSICA SINICA | 2013年 / 62卷 / 02期
基金：
中国国家自然科学基金;
关键词：
quasiclassical trajectory; vector correlations; N plus NO; rotational excitation; POTENTIAL-ENERGY SURFACES; (1)SIGMA(+)(G))+O(P-3) REACTION; BIMOLECULAR REACTIONS; PRODUCT POLARIZATION; ATMOSPHERIC REACTION; AB-INITIO; DYNAMICS; STATE; ALIGNMENT;
D O I：
10.7498/aps.62.023401
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
The stereodynamic properties of the reaction N (S-4)+NO (X-2 Pi) -> N-2 (X-3 Sigma(-)(g))+O (P-3) in different initial reagent rotational states are studied theoretically by using the quasiclassical trajectory method on two lowest (3)A '' and (3)A' potential energy surfaces at a collision energy of 0.6 eV. The vector properties of different rotational states on the two potential energy surfaces are discussed in detail. The results indicate that the rotational excitation of NO has a considerable influence on the stereodynamic property of reaction occurring on the (3)A' potential energy surface, which can be ascribed to the early barrier on this potential energy surface.
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页数：6
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