Microstructure and properties of styrene-butadiene rubber based nanocomposites prepared from an aminosilane modified synthetic lamellar nanofiller

In this work, a novel nanocomposite series based on styrene-butadiene rubber (SBR latex) and alpha-zirconium phosphate(-ZrP) lamellar nanofillers is successfully prepared. The -ZrP lamellar filler is modified at the cation exchange capacity by -aminopropyltrimethoxysilane and the filler surface modification is first discussed. A significant improvement of the mechanical properties is obtained by using the surface modified nanofillers. However, no modification of the gas barrier properties is observed. The impact of addition of bis(triethoxysilylpropyl)tetrasulfide (TESPT) as coupling agent in the system is discussed on the nanofiller dispersion state and on the fillermatrix interfacial bonding. Simultaneous use of modified nanofillers and TESPT coupling agent is found out with extraordinary reinforcing effects on both mechanical and gas barrier properties and the key factors at the origin of the improvement of these properties are identified. (c) 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2013, 51, 10511059