Two-dimensional Structures of Isobutenyl Ether Compounds Possessing Dodecyl and Tridecyl Chains: Effects of Solvent and Tandem Claisen Rearrangement

被引：4
|
作者：
Kikkawa, Yoshihiro [1 ]
Omori, Kazuhiro [1 ,2 ]
Kanesato, Masatoshi [1 ]
Hiratani, Kazuhisa [1 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058562, Japan
[2] Ind Technol Ctr Tochigi Prefecture, Sano, Tochigi 3270847, Japan
来源：
CHEMISTRY LETTERS | 2012年 / 41卷 / 10期
关键词：
SCANNING-TUNNELING-MICROSCOPY; MOLECULAR NANOSTRUCTURES; SURFACES; STM; INTERFACE; CHEMISTRY;
D O I：
10.1246/cl.2012.1196
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two-dimensional (2D) structures of isobutenyl ether compounds possessing relatively short alkyl tails (carbon numbers = 12 and 13) were studied using scanning tunneling microscopy at a solid/liquid interface. Coadsorption of solvent molecules was partly dependent on the alkyl chain lengths of the isobutenyl compounds and solvents. Tandem Claisen rearrangement induced structural convergence, and the solvent effect was completely quenched.
引用
收藏
页码：1196 / 1198
页数：3
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