Synthesis of Quaternized poly(4-Vinyl Pyridine) and the Study of its Ion Exchange Property

被引：8
|
作者：
Chowdhury, P. [1 ]
Saha, S. K. [1 ]
Bayen, S. P. [1 ]
机构：
[1] Visva Bharati, Dept Chem, Synthet Polymer Lab, Santini Ketan 731235, W Bengal, India
来源：
JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY | 2013年 / 50卷 / 09期
关键词：
Polymerization; quaternization; anion selectivity; ion exchanger; POLYMER NETWORKS;
D O I：
10.1080/10601325.2013.813824
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Lightly cross-linked poly(4-vinyl pyridine) has been synthesized from 4-vinyl pyridine and a small amount of ethylene glycol dimethacrylate (EGDMA) in aqueous medium through micelle technique. The polymer is then quaternized with 1,4-dibromobutane to develop an anion exchange resin with high selectivity and ion exchange capacity at a wide range of pH and temperature. The material exhibits high ion exchange capacity and reverse anion selectivity order compared to commercially available anion exchanger. A method has been designed to separate chromate and sulfate using the synthesized material.
引用
收藏
页码：976 / 982
页数：7
相关论文
共 50 条
  • [1] Ion-specific swelling behaviors of partially quaternized poly(4-vinyl pyridine) gel
    Yasumoto, N
    Kasahara, N
    Sakaki, A
    Satoh, M
    COLLOID AND POLYMER SCIENCE, 2006, 284 (08) : 900 - 908
  • [2] Ion-specific swelling behaviors of partially quaternized poly(4-vinyl pyridine) gel
    Naoko Yasumoto
    Naoko Kasahara
    Ayumi Sakaki
    Mitsuru Satoh
    Colloid and Polymer Science, 2006, 284
  • [3] Cyanide detoxification by selective ion exchange with protonated poly(4-vinyl pyridine)
    Chanda, M.
    O'Driscoll, K.F.
    Rempel, G.L.
    Journal of Chemical Technology and Biotechnology, 1983, 33 A (02) : 97 - 108
  • [4] Sorption of sulfide on a macroporous, quaternized poly(4-vinyl pyridine) in alkaline medium
    Univ of Waterloo, Waterloo, Canada
    React Polym, 3 (203-212):
  • [5] CYANIDE DETOXIFICATION BY SELECTIVE ION-EXCHANGE WITH PROTONATED POLY(4-VINYL PYRIDINE)
    CHANDA, M
    ODRISCOLL, KF
    REMPEL, GL
    JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY A-CHEMICAL TECHNOLOGY, 1983, 33 (02): : 97 - 108
  • [6] Modelling of poly(4-vinyl pyridine) and poly(4-vinyl pyridine)/pyridine composites: structural and optical properties
    Vaganova, E.
    Berestetsky, N.
    Yitzchaik, S.
    Goldberg, A.
    MOLECULAR SIMULATION, 2008, 34 (10-15) : 981 - 987
  • [7] ION-EXCHANGE SORPTION OF THIOSULFATE AND TETRATHIONATE ON PROTONATED POLY(4-VINYL PYRIDINE)
    CHANDA, M
    ODRISCOLL, KF
    REMPEL, GL
    REACTIVE POLYMERS, 1984, 2 (04): : 269 - 278
  • [8] Antibacterial behaviour of quaternized poly(vinyl chloride)-g-poly(4-vinyl pyridine) graft copolymers
    Madhumita Patel
    Rajkumar Patel
    Won Seok Chi
    Jong Hak Kim
    Jung-Suk Sung
    Chinese Journal of Polymer Science, 2015, 33 : 265 - 274
  • [9] Antibacterial behaviour of quaternized poly(vinyl chloride)-g-poly(4-vinyl pyridine) graft copolymers
    Patel, Madhumita
    Patel, Rajkumar
    Chi, Won Seok
    Kim, Jong Hak
    Sung, Jung-Suk
    CHINESE JOURNAL OF POLYMER SCIENCE, 2015, 33 (02) : 265 - 274
  • [10] Antibacterial Behaviour of Quaternized Poly(vinyl chloride)-g-Poly(4-vinyl pyridine) Graft Copolymers
    Madhumita Patel
    Rajkumar Patel
    Won Seok Chi
    Jong Hak Kim
    Jung-Suk Sung
    Chinese Journal of Polymer Science, 2015, 33 (02) : 265 - 274
12345