2D LnIII(Nd/La)-AgI Heterometallic and TmIII Homometallic Coordination Polymers Based on Pyridine Dicarboxylate Ligands

被引：3
|
作者：
Zhao, Ling-Zhi [1 ]
Tian, Yuan-Yuan [2 ]
Gong, Ying-Xin [2 ]
Huang, Xiao-Ting [2 ]
Zhang, Fen [2 ]
Rong, Jian-Xiong [2 ]
Cai, Xia [2 ]
Li, Wen-Tao [1 ]
Zeng, Rong-Hua [2 ]
Lu, Dong-Sheng [2 ]
机构：
[1] S China Normal Univ, Lab Nanophoton Funct Mat & Devices, Inst Optoelect Mat & Technol, Guangzhou 510631, Guangdong, Peoples R China
[2] S China Normal Univ, Sch Chem & Environm, Guangzhou 510006, Guangdong, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 01期
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
Hydrothermal synthesis; N; O ligands; Hydrogen bonds; Heterometallic coordination polymers; METAL-ORGANIC FRAMEWORK; LN-AG LN; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURES; ADSORPTION; SEPARATION; COMPLEXES; ACID; PHOTOLUMINESCENCE; LUMINESCENCE;
D O I：
10.1002/zaac.201300197
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two 2D 4d-4f heterometallic coordination polymers, [LnAg(Py26DC)(2)(H2O)(3)]3H(2)O [Ln = Nd (1), La (2); H(2)Py26DC = pyridine-2,6-dicarboxylic acid], and one 2D lanthanide homometallic coordination polymer, [Ln(Py25DC)(ox)(0.5)(H2O)(2)] [Ln = Tm (3); H(2)Py25DC = pyridine-2,5-dicarboxylic acid; ox = oxalate], were synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, and single-crystal X-ray diffraction analysis. Both complexes 1 and 2 are isostructural and exhibit 3-connected 2D heterometallic layer structures with the Schlafli symbol of (8(2)10), whereas complex 3 represents an extended 2D homometallic network structure with (4,4) topology.
引用
收藏
页码：147 / 152
页数：6
相关论文
共 50 条
  • [1] Structural studies and detection of nitroaromatics by luminescent 2D coordination polymers with angular dicarboxylate ligands
    Rachuri, Yadagiri
    Parmar, Bhavesh
    Bisht, Kamal Kumar
    Suresh, Eringathodi
    [J]. INORGANIC CHEMISTRY FRONTIERS, 2015, 2 (03): : 228 - 236
  • [2] Interpenetrating coordination polymers from CuI or AgI and flexible ligands:: 2D polyrotaxanes and interpenetrating grids
    Kasai, Kayoko
    Sato, Mariko
    [J]. CHEMISTRY-AN ASIAN JOURNAL, 2006, 1 (03) : 344 - 348
  • [3] Syntheses, structures and properties of three new two-dimensional CuI-LnIII heterometallic coordination polymers based on 2,2′-dipyridy1-5,5′-dicarboxylate ligands
    Zhao, Junwei
    Cheng, Yamin
    Shang, Sensen
    Zhang, Fang
    Chen, Li
    Chen, Lijuan
    [J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2013, 116 : 348 - 354
  • [4] 1,2,4-Triazolyl-4-acetate: a ditopic ligand combining soft and hard donor sites in homometallic (AgI) and heterometallic (AgI/UVI) coordination polymers
    Senchyk, Ganna A.
    Lysenko, Andrey B.
    Krautscheid, Harald
    Rusanov, Eduard B.
    Karbowiak, Miroslaw
    Domasevitch, Kostiantyn, V
    [J]. CRYSTENGCOMM, 2022, 24 (12) : 2241 - 2250
  • [5] Coordination polymers of the bis(imidazole) ligand modulated by dicarboxylate ligands: From 2D layer to 3D framework
    Yang, Fei-Fei
    Wang, Xiao-Fang
    Yu, Xiao-Yang
    Luo, Yu-Hui
    Zhang, Hong
    [J]. POLYHEDRON, 2015, 98 : 40 - 46
  • [6] Synthesis and structural characterization of homochiral 2D coordination polymers of zinc and copper with conformationally flexible ditopic imidazolium-based dicarboxylate ligands
    Nicasio, Antonio I.
    Montilla, Francisco
    Alvarez, Eleuterio
    Colodrero, Rosario P.
    Galindo, Agustin
    [J]. DALTON TRANSACTIONS, 2017, 46 (02) : 471 - 482
  • [7] Synthesis and Characterization of Two Distinct 2D Nickel(II) Coordination Polymers From Dicarboxylate and Flexible Bis(imidazole) Ligands
    Hu, Ju-Meng
    Zhao, Yan-Qian
    Yu Baoyi
    Van Hecke, Kristof
    Cui, Guang-Hua
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2016, 642 (01): : 41 - 47
  • [8] Synthesis, structure and photoluminescence of three 2D Cd(II) coordination polymers based on varied dicarboxylate ligand
    Wang, Xing-Po
    Han, Lu-Lu
    Lin, Shu-Jie
    Li, Xiao-Yi
    Mei, Kai
    Sun, Di
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 2016, 69 (02) : 286 - 294
  • [9] Two zinc(II)-based coordination polymers with flexible dicarboxylate and pyridine mixed ligands: effect of π•••π interactions on electrical activity
    Akhtaruzzaman
    Das, Pubali
    Khan, Samim
    Maity, Suvendu
    Naaz, Sanobar
    Islam, Sakhiul
    Ghosh, Prasanta
    Ray, Partha Pratim
    Mir, Mohammad Hedayetullah
    [J]. NEW JOURNAL OF CHEMISTRY, 2019, 43 (40) : 16071 - 16077
  • [10] A New Ni(II) Coordination Polymer Based on Imidazole-Containing and Dicarboxylate Ligands with Polycatenated 2D + 2D → 3D Framework
    Yang, Lili
    [J]. SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2016, 46 (08) : 1195 - 1197
12345