Continuous flow photocyclization of stilbenes - scalable synthesis of functionalized phenanthrenes and helicenes

被引：26
|
作者：
Lefebvre, Quentin [1 ]
Jentsch, Marc [1 ]
Rueping, Magnus [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany
来源：
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 9卷
关键词：
continuous-flow reactor; flow chemistry; helicenes; light-driven cyclization reaction; photocyclization; stilbenes; ONE HUNDRED YEARS; STEREOSELECTIVE SYNTHESES; ASYMMETRIC-SYNTHESIS; CARBOHELICENES; LIGHT; PHOTOCHEMISTRY; DERIVATIVES; RESOLUTION; ROUTE;
D O I：
10.3762/bjoc.9.221
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A continuous flow oxidative photocyclization of stilbene derivatives has been developed which allows the scalable synthesis of backbone functionalized phenanthrenes and helicenes of various sizes in good yields.
引用
收藏
页码：1883 / 1890
页数：8
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