Synthesis and x-ray crystal structure determination of the first potassium salt of a primary phosphane: [KP(H)Mes*](x)

被引:59
|
作者
Rabe, GW [1 ]
Yap, GPA [1 ]
Rheingold, AL [1 ]
机构
[1] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716
关键词
D O I
10.1021/ic961420l
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The molecular structure of [KP(H)Mes*](x) [Mes* = 2,4,6-(Bu3C6H2)-Bu-t] features a one-dimensional polymeric ladder-type structure in the solid-state with each alkali metal cation coordinating to the pi-cloud of a neighboring supermesityl ring. This complex represents the first structurally characterized potassium salt of a primary phosphane.
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页码:1990 / &
页数:3
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