Microwave-assisted nitroxide-mediated radical polymerization of styrene

被引：43
|
作者：
Li, J [1 ]
Zhu, XL [1 ]
Zhu, J [1 ]
Cheng, ZP [1 ]
机构：
[1] Suzhou Univ, Sch Chem & Chem Engn, Suzhou 215006, Peoples R China
来源：
RADIATION PHYSICS AND CHEMISTRY | 2006年 / 75卷 / 02期
基金：
高等学校博士学科点专项科研基金;
关键词：
kinetics; living polymerization; microwave irradiation; nitroxide-mediated radical polymerization (NMRP); polystyrene;
D O I：
10.1016/j.radphyschem.2005.06.006
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The first single-mode microwave-assisted nitroxide-mediated radical polymerizations (NMRP) of styrene in bulk were successfully performed. The results showed that the polymerization proceeded in a controlled way. The power of microwave irradiation has considerable effect on the polymerization rate. The polymerization rates under appropriate power of microwave irradiation were faster than that under conventional heating (CH) at the same polymerization temperature. The living nature of the polymer was proved by successful chain extension polymerization and H-1 NMR spectrum analysis. (C) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：253 / 258
页数：6
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