Synthesis and characterization of novel vinyl polymers containing thioester group in side chain

被引：0
|
作者：
Lee, YK [1 ]
Onimura, K [1 ]
Tsutsumi, H [1 ]
Oishi, T [1 ]
机构：
[1] Yamaguchi Univ, Dept Chem Engn & Appl Chem, Yamaguchi 7558611, Japan
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1999年 / 37卷 / 20期
关键词：
radical polymerization; 3-mercaptopropionic acid; styrene; methyl methacrylate; N-cyclohexyl maleimide; glass transition temperature; thioester; optical active polymer;
D O I：
10.1002/(SICI)1099-0518(19991015)37:20<3871::AID-POLA16>3.0.CO;2-P
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Three types of new vinyl monomers, methoxycarbonylethyl thioacrylate (MTA), methoxycarbonylethyl thiomethacrylate (MTM), and methoxycarbonylethyl thiomethacrylate (MnTM), all containing a thioester group in the side chain were synthesized. The monomers were homopolymerized and copolymerized with styrene (St), methyl methacrylate (MMA), or N-cyclohexyl maleimide (CHMI). It was found that byreactions of the thioester groups in the polymerization could not occur. All obtained polymers exhibited only amorphous structures.
引用
收藏
页码：3871 / 3875
页数：5
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