Syntheses, crystal structures and DFT studies of [Me3EM(CO)5] (E = Sb, Bi; M = Cr, W), cis-[(Me3Sb)2Mo(CO)4], and [tBu3BiFe(CO)4]

被引：30

作者：

Breunig, H. J. ^{[1
]}

Borrmann, T. ^{[2
]}

Lork, E. ^{[1
]}

Moldovan, O. ^{[1
]}

Rat, C. I. ^{[3
]}

Wagner, R. P. ^{[1
]}

机构：

[1] Univ Bremen, Inst Anorgan & Phys Chem, Fachbereich 2, D-28334 Bremen, Germany

[2] Univ Bremen, Inst Organ Chem, Fachbereich 2, D-28334 Bremen, Germany

[3] Univ Babes Bolyai, Fac Chem & Chem Engn, Cluj Napoca 400028, Romania

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2009年 / 694卷 / 03期

关键词：

Antimony; Bismuth; Chromium; Iron; Molybdenum; Tungsten; EFFECTIVE CORE POTENTIALS; TRANSITION-METAL; AB-INITIO; COORDINATION-COMPOUNDS; MOLECULAR CALCULATIONS; COMPLEXES; BOND; LIGAND; DERIVATIVES; CHEMISTRY;

D O I：

10.1016/j.jorganchem.2008.11.022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Syntheses of [Me3SbM(CO)(5)] [M = Cr (1), W (2)], [Me3BiM(CO)(5)] [M = Cr (3), W (4)], cis-[(Me3Sb)(2)-Mo(CO)(4)] (5), [(Bu3BiFe)-Bu-t(CO)(4)] (6), crystal structures of 1-6 and DFT studies of 1-4 are reported. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：427 / 432

页数：6

共 50 条

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