Salt metathesis in three dimensional metal-organic frameworks (MOFs) with unprecedented hydrolytic regenerability

被引：46
|
作者：
Kundu, Tanay [1 ]
Sahoo, Subash C. [1 ]
Saha, Subhadeep [1 ]
Banerjee, Rahul [1 ]
机构：
[1] Natl Chem Lab, Phys Mat Chem Div, CSIR, Pune 411008, Maharashtra, India
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 46期
关键词：
COORDINATION POLYMERS; WATER; ADSORBENTS; MOLECULES;
D O I：
10.1039/c3cc41842a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Eight Zn-based porous (1.2 nm) homochiral MOFs (ValZnX, AlaZnX, X = Cl-, Br-, HCO2- and CH3CO2-) were synthesized which possess extremely rare zeolitic (unh) topology. These MOFs show an unprecedented hydrolytic regenerability. Salt metathesis reaction performed on these 3D MOFs in water resulted in 2D coordination polymers (CPs).
引用
收藏
页码：5262 / 5264
页数：3
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