Electro-oxidation of methanol and ethanol using PtRu/C electrocatalysts prepared by spontaneous deposition of platinum on carbon-supported ruthenium nanoparticles

被引：141
|
作者：
Spinacé, E [1 ]
Neto, AO [1 ]
Linardi, M [1 ]
机构：
[1] Ctr Ciencia & Tecnol Mat, CNEN, IPEN, BR-05508900 Sao Paulo, Brazil
来源：
JOURNAL OF POWER SOURCES | 2004年 / 129卷 / 02期
基金：
巴西圣保罗研究基金会;
关键词：
electro-oxidation; ethanol; methanol; PtRu/C electrocatalyst; fuel cell; spontaneous deposition;
D O I：
10.1016/j.jpowsour.2003.11.056
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
PtRu/C electrocatalysts were prepared by spontaneous deposition of Pt(II) and Pt(IV) ions on carbon-supported ruthenium nanoparticles, characterized by EDAX, TEM, cyclic voltammetry and tested for methanol and ethanol oxidation using the thin porous coating technique. The spontaneous deposition of Pt(II) ions was about two times more effective than Pt(IV) ions. The electrocatalysts were active for methanol and ethanol oxidation. For methanol oxidation good performance was obtained with high platinum coverage and for ethanol oxidation with low platinum coverage. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：121 / 126
页数：6
相关论文
共 50 条
  • [1] Preparation of methanol oxidation electrocatalysts: ruthenium deposition on carbon-supported platinum nanoparticles
    F. Maillard
    F. Gloaguen
    J-M. Leger
    [J]. Journal of Applied Electrochemistry, 2003, 33 : 1 - 8
  • [2] Preparation of methanol oxidation electrocatalysts: ruthenium deposition on carbon-supported platinum nanoparticles
    Maillard, F
    Gloaguen, F
    Leger, JM
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 2003, 33 (01) : 1 - 8
  • [3] Methanol Electro-Oxidation on Carbon-Supported PtRu Nanowires
    Almeida, Glaucia R. O.
    Lopez-Suarez, Franz E.
    Silva, Lays S. R.
    Pereira, Gabriel F.
    Bueno-Lopez, Agustin
    Eguiluz, Katlin I. B.
    Salazar-Banda, Giancarlo R.
    [J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2019, 19 (02) : 795 - 802
  • [4] Carbon monoxide, methanol and ethanol electro-oxidation on Ru-decorated carbon-supported Pt nanoparticles prepared by spontaneous deposition
    Velazquez-Palenzuela, Amado
    Brillas, Enric
    Arias, Conchita
    Centellas, Francesc
    Antonio Garrido, Jose
    Maria Rodriguez, Rosa
    Cabot, Pere-Lluis
    [J]. JOURNAL OF POWER SOURCES, 2013, 225 : 163 - 171
  • [5] PtRu Nanoparticles Supported on Phosphorous-Doped Carbon as Electrocatalysts for Methanol Electro-Oxidation
    Viviane Santos Pereira
    Julio C. M. da Silva
    Almir Oliveira Neto
    Estevam V. Spinacé
    [J]. Electrocatalysis, 2017, 8 : 245 - 251
  • [6] PtRu Nanoparticles Supported on Phosphorous-Doped Carbon as Electrocatalysts for Methanol Electro-Oxidation
    Pereira, Viviane Santos
    da Silva, Julio C. M.
    Oliveira Neto, Almir
    Spinace, Estevam V.
    [J]. ELECTROCATALYSIS, 2017, 8 (03) : 245 - 251
  • [7] Electro-oxidation of ethanol using PtRu/C electrocatalysts prepared by alcohol-reduction process
    Spinacé, EV
    Neto, AO
    Vasconcelos, TRR
    Linardi, M
    [J]. JOURNAL OF POWER SOURCES, 2004, 137 (01) : 17 - 23
  • [8] Electro-oxidation of methanol and ethanol using PtRu/C, PtSn/C and PtSnRu/C electrocatalysts prepared by an alcohol-reduction process
    Oliveira Neto, Almir
    Dias, Ricardo R.
    Tusi, Marcelo M.
    Linardi, Marcelo
    Spinace, Estevarn V.
    [J]. JOURNAL OF POWER SOURCES, 2007, 166 (01) : 87 - 91
  • [9] Electro-oxidation of methanol and ethanol on carbon-supported Pt catalyst at intermediate temperature
    Otomo, Junichiro
    Nishida, Satoru
    Takahashi, Hiroshi
    Nagamoto, Hidetoshi
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2008, 615 (01) : 84 - 90
  • [10] Effect of structure of carbon-supported PtRu electrocatalysts on the electrochemical oxidation of methanol
    Takasu, Y
    Fujiwara, T
    Murakami, Y
    Sasaki, K
    Oguri, M
    Asaki, T
    Sugimoto, W
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (12) : 4421 - 4427
12345