LEAST SQUARES REGRESSION WITH ERRORS IN BOTH VARIABLES: CASE STUDIES

被引:14
|
作者
de Oliveira, Elcio Cruz [1 ,2 ]
de Aguiar, Paula Fernandes [3 ]
机构
[1] Petrobras Transporte SA, BR-20091060 Rio De Janeiro, RJ, Brazil
[2] Pontificia Univ Catolica Rio de Janeiro, BR-22453900 Rio De Janeiro, RJ, Brazil
[3] Univ Fed Rio de Janeiro, Inst Quim, BR-21945970 Rio De Janeiro, RJ, Brazil
来源
QUIMICA NOVA | 2013年 / 36卷 / 06期
关键词
orthogonal distance regression; least squares regression; error in x and y variables; LINEAR-REGRESSION; CALIBRATION;
D O I
10.1590/S0100-40422013000600025
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Analytical curves are normally obtained from discrete data by least squares regression. The least squares regression of data involving significant error in both x and y values should not be implemented by ordinary least squares (OLS). In this work, the use of orthogonal distance regression (ODR) is discussed as an alternative approach in order to take into account the error in the x variable. Four examples are presented to illustrate deviation between the results from both regression methods. The examples studied show that, in some situations, ODR coefficients must substitute for those of OLS, and, in other situations, the difference is not significant.
引用
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页码:885 / 889
页数:5
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