Electrogenerated chemiluminescence using platinum electrodes with hydrogen peroxide pre-treatment

被引:8
|
作者
Kearney, NJ [1 ]
Hall, CE [1 ]
Jewsbury, RA [1 ]
Timmis, SG [1 ]
机构
[1] UNIV HUDDERSFIELD,DEPT CHEM & BIOL SCI,HUDDERSFIELD HD1 3DH,W YORKSHIRE,ENGLAND
来源
ANALYTICAL COMMUNICATIONS | 1996年 / 33卷 / 08期
关键词
D O I
10.1039/ac9963300269
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A novel hydrogen peroxide pre-treatment of platinum electrodes is described, The method is applied to the electrogenerated chemiluminescence of luminol using air-segmented flow and an improved response and precision are reported, A rectilinear calibration for luminol is reported from 10(-10) mol dm(-3) to 10(-5) mol dm(-3) with a LOD of 1 x 10(-10) mol dm(-3). An explanation in terms of surface effects on the electrode surface is given, supported by cyclic voltammetry results.
引用
收藏
页码:269 / 270
页数:2
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