Electrospray mass spectrometry for actinides and lanthanide speciation

被引：20
|
作者：
Moulin, C [1 ]
Amekraz, B [1 ]
Colette, S [1 ]
Doizi, D [1 ]
Jacopin, C [1 ]
Lamouroux, C [1 ]
Plancque, G [1 ]
机构：
[1] CEA Saclay, Direct Nucl Energy, Dept Physicochem,Lab Speciat Radionuclides & Mol, Serv Studies Radionuclides Behav, F-91191 Gif Sur Yvette, France
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2006年 / 408卷
关键词：
actinide; lanthanide; fluorescence; speciation; electrospray mass spectrometry;
D O I：
10.1016/j.jallcom.2005.04.177
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Electrospray mass spectrometry (ES-MS) is a new speciation technique that has the great interest to be able to probe the element, the ligand and the complex in order to reach the speciation. This paper will focus on the use of ES-MS for the speciation of actinides/lanthanides on several systems of interest in various fields such as the interaction between DTPA (decorporant) and europium, HEBP and uranium, BTP (new extracting agent) and lanthanides with comparison with known chemistry as well as whenever possible with other speciation techniques. (c) 2005 Elsevier B.V. All rights reserved.
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页码：1242 / 1245
页数：4
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