A "Looking Glass" into Electrolyte Properties: Acetonitrile-Lithium Salt (AN-LiX) Mixtures

被引:0
|
作者
Seo, D. [1 ]
Han, S. -D. [1 ]
Ly, Q. [1 ]
Henderson, W. A. [1 ]
机构
[1] N Carolina State Univ, Dept Chem & Biomol Engn, ILEET Lab, Raleigh, NC 27695 USA
来源
NON-AQUEOUS ELECTROLYTES FOR LITHIUM BATTERIES | 2011年 / 33卷 / 28期
关键词
D O I
10.1149/1.3563091
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Phase diagrams have been prepared for acetonitrile mixtures with either LiBF4 or LiClO4. Crystalline solvate structures were determined to complement the phase diagrams and provide additional insight into variations in Li+ cation coordination in the solid-state. This information has then been utilized to aid in understanding the solvation and ionic association of Li+ cations in the liquid-state.
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页码:71 / 76
页数:6
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