An experimental and theoretical study of the molecular structure and vibrational spectra of iodotrimethylsilane (SiIMe3)

被引：8
|
作者：
Montejo, M
Hinchley, SL
Ben Altabef, A
Robertson, HE
Ureña, FP
Rankin, DWH
González, JJL
机构：
[1] Univ Jaen, Fac Ciencias Expt, Dept Quim Fis & Analit, Jaen 23071, Spain
[2] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
[3] Univ Nacl Tucuman, Fac Bioquim Ouim & Farm, Inst Quim Fis, RA-4000 San Miguel De Tucuman, Argentina
来源：
PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2006年 / 8卷 / 04期
关键词：
D O I：
10.1039/b510827f
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The gas-phase molecular structure of iodotrimethylsilane (ITMS) has been determined from electron diffraction data. Infrared and Raman spectra have been completely assigned. The experimental work is supported by ab initio HF and MP2 calculations for the gas-phase structure determination and DFT(B3LYP) calculations, combined with Pulay's SQM method, for the vibrational spectra data.
引用
收藏
页码：477 / 485
页数：9
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