Synthesis and spectroscopic characterization of tin(IV) and organotin(IV) derivatives of bis(azol-1-yl)methanes

被引：0
|
作者：
Pettinari, C [1 ]
机构：
[1] UNIV CAMERINO,DIPARTIMENTO SCI CHIM,I-62032 CAMERINO,MACERATA,ITALY
来源：
MAIN GROUP METAL CHEMISTRY | 1996年 / 19卷 / 08期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of 1:1 adducts of the type [(L)R(n)SnX(4-n)]. yH(2)O (L = bis(imidazol-1-yl)methane (L(I)) or bis(1,2,4-triazol-1-il)methane (L(T));R = Me, Et, Bu(n) or Ph; X = I, Br or Cl; n = 0, 1, 2 or 3; y = O, 1, 1.5 or 2) have been synthesized and characterized in the solid state and in solution by analyses, spectral (IR, far-IR, H-1 and Sn-119 NMR) data and conductivity measurements. Some of them are likely polymeric in the solid state. The tri- and di-organotin(IV) compounds generally dissociate in DMSO solution, while the tri- and tetrahalide adducts partially retain the hexacoordinate configuration.
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页码：489 / 498
页数：10
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