Efficient and highly selective oxidation of sulfides to sulfoxides in the presence of an ionic liquid containing hypervalent iodine

被引：39
|
作者：
Qian, WX [1 ]
Pei, L [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310028, Zhejiang, Peoples R China
来源：
SYNLETT | 2006年 / 05期
关键词：
hypervalent iodine reagent; sulfides; sulfoxides; oxidation; ionic liquids;
D O I：
10.1055/s-2006-933109
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A mild, efficient, highly selective, and environmentally friendly oxidation of sulfides to sulfoxides with a recyclable ion-supported hypervalent iodine reagent has been developed. This reaction is tolerant of hydroxyl, nitrile, methoxy, carbon-carbon double bonds, and ester functionalities. Aliphatic and aromatic Sulfides are selectively oxidized to the corresponding sulfoxides at room temperature in excellent yields.
引用
收藏
页码：709 / 712
页数：4
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