Amido pincer complexes of palladium: Synthesis, structure, and catalytic Heck reaction

被引:95
|
作者
Huang, MH
Liang, LC [1 ]
机构
[1] Natl Sun Yat Sen Univ, Dept Chem, Kaohsiung 80424, Taiwan
[2] Natl Sun Yat Sen Univ, Ctr Nanosci & Nanotechnol, Kaohsiung 80424, Taiwan
关键词
D O I
10.1021/om049888g
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Palladium complexes containing an o-phenylene-derived amido diphosphine ligand efficiently catalyze the Heck olefination of a wide array of aryl halides, leading to extremely high turnover numbers of up to 4.5 x 10(7).
引用
收藏
页码:2813 / 2816
页数:4
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