Complexes of Co(II), Ni(II), Cu(II), and Pd(II) with Sulfametrole-Cyclodiphosph(V)azane Derivatives

Novel [1,3-di-[N1-4-methoxy-1,2,5-thiadiazole-3-yl-sulfanilamide(sulfametrole)]2,,4-bis-[1,3-dithiole-2-thione-4,5-dithiolate]-2 ',4 '-dichlorocyclodiphosph(V)azane] (III), was prepared and their coordinating behavior towards the metal ions Co(II), Ni(II), Cu(II), and Pd(II) was studied. The structures of the isolated products are proposed based on elemental analyses, IR, UV, H-1, and P-31 NMR, ESR, magnetic susceptibility, molar ratio, conductometric titration and electrical conductivity measurements. The prepared complexes showed high to moderate bactericidal activity compared with the ligand.