Complexes of boron with catechol: The X-ray crystal structure of Meulenhoff's salt, 2{(pyH)[B(cat)(2)]center dot H2cat}center dot H2O

被引：15
|
作者：
Griffith, WP [1 ]
White, AJP [1 ]
Williams, DJ [1 ]
机构：
[1] UNIV LONDON IMPERIAL COLL SCI & TECHNOL,DEPT CHEM,INORGAN & CHEM CRYSTALLOG RES LABS,LONDON SW7 2AY,ENGLAND
来源：
POLYHEDRON | 1996年 / 15卷 / 17期
基金：
英国工程与自然科学研究理事会;
关键词：
D O I：
10.1016/0277-5387(95)00590-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Meulenhoff's salt 2 {(pyH)[B(cat)(2)]. H(2)cat}. H2O (1), has been prepared by the original literature method and its X-ray crystal structure determined. The stoichiometry is confirmed as 1:1:3 pyridine:boron: catechol, (H(2)cat, 1,2-dihydroxybenzene), though only two of the catechol units are bound directly to the boron centre. The IR and Raman vibrational spectra of the solid and the H-1, C-13{H-1} and B-11{H-1} NMR spectra of the complex in solution are reported, and suggest that the solid state structure of the anion of 1 is maintained in solution. (C) 1996 Published by Elsevier Science Ltd.
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收藏
页码：2835 / 2839
页数：5
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