Electroanalytical properties of the sams of quinone derivatized calix[4]arene carboxylic acids on silver electrode

被引：0
|
作者：
Kang, SK [1 ]
Chung, TD [1 ]
Kim, H [1 ]
机构：
[1] Seoul Natl Univ, Dept Chem, Seoul 151742, South Korea
来源：
PROCEEDINGS OF THE SYMPOSIUM ON NEW DIRECTIONS IN ELECTROANALYTICAL CHEMISTRY II | 1999年 / 99卷 / 05期
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D O I：
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中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Water-soluble redox-active calix[4]arenes with carboxylic groups were prepared and spontaneous adsorption on silver surface was observed. Due to the novel structure, the calix[4]arenes exhibited selective affinity towards calcium ion in aqueous media. When the annular ionophores were immobilized on the surface, voltammetric and spectroscopic studies showed the entrapment of calcium ion. And it is possible to capture and remove the ion reversibly using strong chelating agents such as ethylenediaminetetraacetic acid (EDTA).
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页码：259 / 263
页数：5
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