Binuclear CC Cyclometalated Platinum(II) NHC Complexes with Bridging Amidinate Ligands

被引：36

作者：

Leopold, Hendrik ^{[1
]}

Tenne, Mario ^{[1
]}

Tronnier, Alexander ^{[1
]}

Metz, Stefan ^{[2
]}

Muenster, Ingo ^{[2
]}

Wagenblast, Gerhard ^{[2
]}

Strassner, Thomas ^{[1
]}

机构：

[1] Tech Univ Dresden, Phys Organ Chem, D-01069 Dresden, Germany

[2] BASF SE, D-67056 Ludwigshafen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2016年 / 55卷 / 51期

关键词：

amidinates; luminescence; N-heterocyclic carbenes; OLEDs; platinum; PHOTOPHYSICAL PROPERTIES; IRIDIUM(III) COMPLEXES; METAL-COMPLEXES; PHOSPHORESCENCE; EFFICIENCY; LIGHT; PHOTOLUMINESCENCE; MANAGEMENT; GREEN; STATE;

D O I：

10.1002/anie.201607075

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Binuclear (CC)-C-boolean AND* cyclometalated NHC platinum(II) compounds with bridging amidinate ligands were synthesized to evaluate their photophysical properties. Their three-dimensional structures were determined by a combination of 2D NMR experiments, mass spectrometry, DFT calculations, and solid-state structure analysis. The bridging amidinate ligands enforce short distances between the platinum centers of the two cyclometalated structures, which gives rise to extraordinary photophysical properties.

引用

页码：15779 / 15782

页数：4

共 50 条

[1] Phosphorescent Platinum(II) Complexes with CC Cyclometalated NHC Ligands
Strassner, Thomas
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2016, 49 (12) : 2680 - 2689
[2] cyclometalated mesoionic NHC ligands in phosphorescent platinum(II) complexes
Soellner, Johannes
Strassner, Thomas
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
[3] Ruthenium(II) DMSO complexes with CC cyclometalated phenylimidazol NHC ligands
Schleicher, David
Leopold, Hendrik
Strassner, Thomas
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2017, 829 : 101 - 107
[4] C C* Cyclometalated Platinum(II) NHC Complexes with β-Ketoimine Ligands
Tronnier, Alexander
Poethig, Alexander
Herdtweck, Eberhardt
Strassner, Thomas
[J]. ORGANOMETALLICS, 2014, 33 (04) : 898 - 908
[5] Synthesis and Catalysis of NHC Coordinated Cyclometalated Palladium(II) Complexes with Bridging Hydroxide Ligands
Nakajima, Isami
Shimizu, Minori
Okuda, Yuta
Akiyama, Ryo
Tadano, Ryu
Nagaoka, Masahiro
Uemura, Naohiro
Yoshida, Yasushi
Mino, Takashi
Shinozaki, Hiraku
Yamamoto, Tetsuya
[J]. ADVANCED SYNTHESIS & CATALYSIS, 2022, 364 (10) : 1763 - 1768
[6] C∧C* cyclometalated platinum(II) NHC complexes
Strassner, Thomas
Tronnier, Alexander
Tenne, Mario
Soellner, Johannes
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
[7] Ruthenium(II) Bipyridyl Complexes with Cyclometalated NHC Ligands
Schleicher, David
Leopold, Hendrik
Borrmann, Horst
Strassner, Thomas
[J]. INORGANIC CHEMISTRY, 2017, 56 (12) : 7217 - 7229
[8] Synthesis and Characterization of Cyclometalated NHC Platinum Complexes with Chelating Carboxylate Ligands
Zabransky, Martin
Soellner, Johannes
Horky, Filip
Cisarova, Ivana
Stepnicka, Petr
Strassner, Thomas
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 2019 (17) : 2284 - 2290
[9] A potential strategy used for controlling the phosphorescence quantum yield of cyclometalated (CC) platinum(II) NHC complexes: The theoretical insight
Zuo, Ke
Luo, Yafei
Sun, Xin
Shen, Wei
Tang, Dianyong
Hu, Jianping
[J]. ORGANIC ELECTRONICS, 2018, 57 : 367 - 376
[10] Enlarging the π System of Phosphorescent (C∧C*) Cyclometalated Platinum(II) NHC Complexes
Tronnier, Alexander
Poethig, Alexander
Metz, Stefan
Wagenblast, Gerhard
Muenster, Ingo
Strassner, Thomas
[J]. INORGANIC CHEMISTRY, 2014, 53 (12) : 6346 - 6356

← 1 2 3 4 5 →